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Question: Draw a valid Lewis structure for each species.

a.CH3CH3b.CH5Nc.CH3Cl

Short Answer

Expert verified

Answer

a. The Lewis structure of CH3CH3is shown below:


Lewis structure of ethane

b. The Lewis structure of isCH5Nshown below:

Lewis structure of methanamine

c. The Lewis structure of CH3Clis shown below:

Lewis structure of chloromethane

Step by step solution

01

 Step-by-Step Solution Step 1: Meaning of Lewis structure

Lewis structure is the representation of the outermost electron and the bond formed by the element. In the representation, dots and lines are used to represent the valence electrons and bond, respectively

02

Lewis structure of a.

The given species isCH3CH3 . The valence electrons in C and H are 4 and 1, respectively. The total valence electrons in the given species are calculated as follows:

Each carbon shares its electrons with other carbon and 3 H atoms. The Lewis structure is shown below:

Lewis structure of ethane

03

Lewis structure of b.

The given species isCH5N . The valence electrons in C and N are 4 and 5, respectively. The total valence electrons in the given species are calculated as follows:
TotalValenceElectrons=4+5(1)+5=9+5=14

Carbon shares its electrons with 3 H atoms and 1 N atom. N shares an electron with each H atom, and there will be two nonbonding electrons on N. The Lewis structure CH5N is shown below:

Lewis structure of methanamine

04

Lewis structure of c. 

The given species isCH3Cl. The valence electrons in C, H, and Cl are 4, 1, and 7, respectively. The total valence electrons in the given species are calculated as follows:

TotalValenceElectrons=4+3(1)+7=7+7=14

Carbon shares its electrons with 3 H atoms and 1 Cl atom. Cl shares an electron with a C atom, and there will be six nonbonding electrons on Cl. The Lewis structure CH3Cl is shown below:

Lewis structure of chloromethane

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Most popular questions from this chapter

Question: While the most common isotope of nitrogen has a mass number of 14 (nitrogen-14), a radioactive isotope of nitrogen has a mass number of 13 (nitrogen-13). Nitrogen-13 is used in PET (positron emission tomography) scans by physicians to monitor brain activity and diagnose dementia. For each isotope, give the following information: (a) the number of protons; (b) the number of neutrons; (c) the number of electrons in the neutral atom; (d) the group number; and (e) the number of valence electrons.

Question: Follow the curved arrows to draw a second resonance structure for each species.

a.

b.

Question: Consider the compounds and ions with curved arrows drawn below. When the curved arrows give a second valid resonance structure, draw the resonance structure. When the curved arrows generate an invalid Lewis structure, explain why the structure is unacceptable.

a.

b.

c.

d.

Question: The curved arrow notation introduced in Section 1.6 is a powerful method used by organic chemists to show the movement of electrons not only in resonance structures but also in chemical reactions. Since each curved arrow shows the movement of two electrons, following the curved arrows illustrates what bonds are broken and formed in a reaction. Consider the following three-step process: (a) Add curved arrows in Step [1] to show the movement of electrons. (b) Use the curved arrows drawn in Step [2] to identify the structure of X; X is converted in Step [3] to phenol and HCl.

Question: Anacin is an over-the-counter pain reliever that contains aspirin and caffeine. Answer the following questions about each compound:

a. What is the molecular formula?

b. How many lone pairs are present on heteroatoms?

c. Label the hybridization state of each carbon.

d. Draw three additional resonance structures.

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