Chapter 5: Q4. (page 180)
Draw in a plane of symmetry for each molecule.
a.
b.
c.
d.
Short Answer
a.
b.
c.
d.
Chapter 5: Q4. (page 180)
Draw in a plane of symmetry for each molecule.
a.
b.
c.
d.
a.
b.
c.
d.
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Get started for freeDraw the structures of (S,S)-ethambutol, a drug used to treat tuberculosis that is 10 times more potant than any of its other isomers.
ethambutol
Determine if each compound is identical to or an enantiomer of A.
a.
b.
c.
Without drawing out the structures, label each pair of compounds as enantiomers or diastereomers.
a. (2R,3S)-hexane-2,3-diol and (2R,3R)-hexane-2,3-diol
b. (2R,3R)-hexane-2,3-diol and (2S,3S)-hexane-2,3-diol
c. (2R,3S,4R)-hexane-2,3,4-triol and (2S,3R,4R)-hexane-2,3,4-triol
Draw all the possible stereoisomers for each compound and label pairs of enantiomers and diastereomers.
a.
b.
The amino acid (S)-alanine has the physical characteristics listed under the structure.
a. What is the melting point of (R)-alanine?
b. How does the melting point of a racemic mixture of (R)- and (S)-alanine compare to the melting point of (S)-alanine?
c. What is the specific rotation of (R)-alanine, recorded under the same conditions as the reported rotation of (S)-alanine?
d. What is the optical rotation of a racemic mixture of (R)- and (S)-alanine?
e. Label each of the following as optically active or inactive: a solution of pure (S)-alanine; an equal mixture of (R)- and (S)-alanine; a solution that contains 75% (S)- and 25% (R)-alanine.
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