Chapter 5: Q4. (page 180)
Draw in a plane of symmetry for each molecule.
a.
b.
c.
d.
Short Answer
a.
b.
c.
d.
Chapter 5: Q4. (page 180)
Draw in a plane of symmetry for each molecule.
a.
b.
c.
d.
a.
b.
c.
d.
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Get started for freeThe facts in Section 5.4A can be used to locate stereogenic centers in any molecule, no matter how complicated. Always look for carbons surrounded by four different groups. With this in mind, locate the four stereogenic centers in aliskiren, a drug introduced in 2007 for the treatment of hypertension.
If the two stereogenic centers of a compound are R,S in configuration, what are the R,S assignments for its enantiomer and two diastereomers?
Pure MSG, a common flavor enhancer, exhibits a specific rotation of +24. (a) Calculate the ee of a solution whose is +10. (b) If the ee of a solution of MSG is 80%, what is for this solution?
MSG
monosodium glutamate
Locate the tetrahedral stereogenic center(s) in each compound. A molecule may have one or more stereogenic centers.
a.
b.
c.
d.
e.
f.
State how each pair of compounds is related. Are they enantiomers, diastereomers, constitutional isomers, or identical?
a.
b.
c.
d.
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