Chapter 15: Q68. (page 570)
Question: What monomer is needed to form each polymer?
a.
b.
Answer
a.
b.
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Question. Devise a synthesis of hexane-2,3-diol from propane as the only source of carbon atoms. You may use any other required organic or inorganic reagents.
Question:Draw the products formed in each reaction and include the stereochemistry around any stereogenic centers.
a.
b.
c.
d.
Question: When 3,3-dimethylbut-1-ene is treated with HBr alone, the major product is 2-bromo-2,3- dimethylbutane. When the same alkene is treated with HBr and peroxide, the sole product is 1-bromo-3,3-dimethylbutane. Explain these results by referring to the mechanisms.
Question: Draw resonance structures for each radical.
a.
b.
c.
Question: When two monomers (X and Y) are polymerized together, a copolymer results. An alternating copolymer is formed when the two monomers X and Y alternate regularly in the polymer chain. Draw the structure of the alternating copolymer formed when the two monomers, CH2CCl2 and CH2,=CHC6H5 are polymerized together.
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