Chapter 15: Q6. (page 570)
Question: Using Mechanism 15.1 as a guide, write the mechanism for the reaction of CH4with Br2 to form CH3 Br and HBr. Classify each step as initiation, propagation, or termination.
Short Answer
Answer
Chapter 15: Q6. (page 570)
Question: Using Mechanism 15.1 as a guide, write the mechanism for the reaction of CH4with Br2 to form CH3 Br and HBr. Classify each step as initiation, propagation, or termination.
Answer
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Get started for freeQuestion: Draw the products formed when a chlorine atom reacts with each species.
a.
b.
c.
d. O2
Question: When HBr adds to (CH3)2C=CH2 under radical conditions, two radicals are possible products in the first step of chain propagation. Draw the structure of both radicals and indicate which one is formed. Then draw the preferred product from HBr addition under radical conditions.
Question: Draw a stepwise mechanism for the following polymerization reaction
Question: When 3,3-dimethylbut-1-ene is treated with HBr alone, the major product is 2-bromo-2,3- dimethylbutane. When the same alkene is treated with HBr and peroxide, the sole product is 1-bromo-3,3-dimethylbutane. Explain these results by referring to the mechanisms.
Question: With reference to the indicated C-H bonds in 2-methylbutane.
a. Rank the C-H bonds in order of increasing bond length.
b. Draw the radical resulting from cleavage of each C-H bond and classify it as 10,20, or 30
c.Rank the order of radicals in order of increasing stability.
Rank the C-H bonds in order of increasing ease of H abstractions in a radical halogenation reaction.
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