Chapter 15: Q37. (page 570)
Question: What alkane is needed to make each alkyl halide by radical halogenation?
Short Answer
Answer
Chapter 15: Q37. (page 570)
Question: What alkane is needed to make each alkyl halide by radical halogenation?
Answer
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Get started for freeQuestion: Identify the structure of a minor product formed from the radical chlorination of propane, which has molecular formula C3H6Cl2 and exhibits the given 1H NMR spectrum.
Question: Draw all resonance structures of the radical that results from abstraction of a hydrogen atom from the antioxidant BHA (butylated hydroxy anisole).
Question: With reference to the indicated C-H bonds in 2-methylbutane.
a. Rank the C-H bonds in order of increasing bond length.
b. Draw the radical resulting from cleavage of each C-H bond and classify it as 10,20, or 30
c.Rank the order of radicals in order of increasing stability.
Rank the C-H bonds in order of increasing ease of H abstractions in a radical halogenation reaction.
Question: (a)Hard contact lenses, which first became popular in the 1960s, were made by polymerizing methyl methacrylate [CH2=C(CH3)CO2CH3] to form poly(methyl methacrylate) (PMMA). Draw the structure of PMMA. (b) More comfortable softer contact lenses introduced in the 1970swere made by polymerizing hydroxyethyl methacrylate [CH2=C(CH3)CO2CH2CH2OH] to form
poly(hydroxyethyl methacrylate) (poly-HEMA). Draw the structure of poly-HEMA. Since neither polymer allows oxygen from the air to pass through to the retina, newer contact lenses that are both comfortable and oxygen-permeable have now been developed.
Question: Show all steps and reagents needed to convert cyclohexane into each compound: (a) the two enantiomers of trans-1,2-dibromocyclohexane; and (b) 1,2-epoxycyclohexane.
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