Chapter 15: Q22. (page 570)
Question: Rosmarinic acid is an antioxidant isolated from rosemary. Draw resonance structures for the radical that results from removal of the labeled H atom in rosmarinic acid.
Short Answer
Answer
Chapter 15: Q22. (page 570)
Question: Rosmarinic acid is an antioxidant isolated from rosemary. Draw resonance structures for the radical that results from removal of the labeled H atom in rosmarinic acid.
Answer
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Get started for freeQuestion:What reagents are needed to convert cyclopentene into
(a)bromocyclopentane;
(b) trans-1,2-dibromocyclopentane;
(c) 3-bromocyclopentene?
Question:Draw the products formed in each reaction and include the stereochemistry around any stereogenic centers.
a.
b.
c.
d.
Question: Consider the following Bromination:
(CH)3 CH +Br2(CH3)3 CBr +HBr
(a) Calculate ฮHยฐ for this reaction by using the bond dissociation energies in Table 6.2. (b) Draw out a stepwise mechanism for the reaction, including the initiation, propagation, and termination steps. (c) Calculate ฮHยฐ for each propagation step. (d) Draw an energy diagram for the propagation steps. (e) Draw the structure of the transition state of each propagation step.
Question: In cells, vitamin C exists largely as its conjugate base X. X is an antioxidant because radicals formed in oxidation processes abstract the labeled H atom, forming a new radical that haltsoxidation. Draw the structure of the radical formed by H abstraction, and explain why this Hatom is most easily removed.
Question: Explain why radical bromination of p-xylene forms C rather than D.
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