Chapter 15: Q14. (page 570)
Question: Draw the monochlorination products formed when each compound is heated with Cl2. Include the stereochemistry at any stereogenic center.
a.
b.
c.
d.
Short Answer
Answer
a.
b.
c.
d.
Chapter 15: Q14. (page 570)
Question: Draw the monochlorination products formed when each compound is heated with Cl2. Include the stereochemistry at any stereogenic center.
a.
b.
c.
d.
Answer
a.
b.
c.
d.
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Get started for freeQuestion: Which compounds can be prepared in good yield by allylic halogenation of an alkene?
a.
b.
c.
Question: PGF2 (Section 4.15) is synthesized in cells from arachidonic acid C20H32O2 using a cyclooxygenase enzyme that catalyzes a multistep radical pathway. Part of this process involves the conversion of radical A to PGG2, an unstable intermediate, which is then transformed to PGF2 and other prostaglandins. Draw a stepwise mechanism for the conversion of A to PGG2 . (Hint: The mechanism begins with radical addition to a carbon-carbon double bond to form a resonance-stabilized radical.
Question: Reaction of (CH3 )3 CH with Cl2 forms two products: (CH3 )2 CHCH2Cl (63%) and (CH3)3 CCl (37%). Why is the major product formed by cleavage of the stronger 1ยฐ C-H bond?
Question: When two monomers (X and Y) are polymerized together, a copolymer results. An alternating copolymer is formed when the two monomers X and Y alternate regularly in the polymer chain. Draw the structure of the alternating copolymer formed when the two monomers, CH2CCl2 and CH2,=CHC6H5 are polymerized together.
Questions: Rank the indicated hydrogen atoms in order of increasing ease of abstraction in a radical halogenation reaction.
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