Chapter 12: Q.63. (page 492)
Question:Devise a synthesis of each compound from acetylene and any other required reagents.
Short Answer
Answer
Chapter 12: Q.63. (page 492)
Question:Devise a synthesis of each compound from acetylene and any other required reagents.
Answer
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Get started for freeQuestion: Stearidonic acid (C18H28O2 ) is an unsaturated fatty acid obtained from oils isolated from hemp and blackcurrant (see also Problem 10.11).
a. What fatty acid is formed when Stearidonic acid is hydrogenated with excess H2 and a Pd catalyst?
b. What fatty acids are formed when stearidonic acid is hydrogenated with one equivalent of H2 and a Pd catalyst?
c. Draw the structure of a possible product formed when stearidonic acid is hydrogenated with one equivalent of H2 and a Pd catalyst, and one double bond is isomerized to a trans isomer.
d. How do the melting points of the following fatty acids compare: stearidonic acid; one of the products formed in part (b); the product drawn in part (c)?
Question: Identify the starting material in each reaction.
a.
b.
Question: Which alkene in each pair has the larger Heat of hydrogenation?
a.
b.
Question: Devise a synthesis of the following compound from acetylene and organic compounds containing two carbons or fewer. You may use any other required reagents.
Question: Dihydroxylation of an alkene can be carried out with in . In this reaction, transbut-2-ene affords (2R,3S)-butane-2,3-diol, whereas cis-but-2-ene affords a mixture of (2R,3R)-butane-2,3-diol and (2S,3S)-butane-2,3-diol. Does dihydroxylation by this method occur with syn or anti addition?
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