Chapter 12: PROBLEM 12.50 (page 490)
Question: Identify the starting material in each reaction.
a.
b.
Short Answer
Answer
a.
b.
Chapter 12: PROBLEM 12.50 (page 490)
Question: Identify the starting material in each reaction.
a.
b.
Answer
a.
b.
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Get started for freeQuestion: Oximene and myrcene, two hydrocarbons isolated from alfalfa that have the molecular formula , both yield 2,6-dimethyloctane when treated with and a Pd catalyst. Ozonolysis of oximene forms , , and . Ozonolysis of myrcene yields , (two equiv), and . Identify the structures of oximene and myrcene.
Question: Identify compounds A, B, and C.
a. Compound A has molecular formula and reacts with two equivalents of . A gives as the only product of oxidative cleavage with followed by.
b. Compound B has molecular formula and gives when treated with excess in the presence of Pd. B reacts with and to form compound C (molecular formula ).
Question: Draw the products formed in each oxidative cleavage.
a.
b.
c.
d.
Question: DHA is a fatty acid derived from fish oil and an abundant fatty acid in vertebrate brains. Hydrogenation of DHA forms docosanoic acid and ozonolysis forms (five equivalents), and . What is the structure of DHA if all double bonds have the Zconfiguration?
Question: The Birch reduction is a dissolving metal reaction that converts substituted benzenes to cyclohexa-1,4-dienes using Li and liquid ammonia in the presence of an alcohol. Draw a stepwise mechanism for the following Birch reduction.
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