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Chapter 12: PROBLEM 12.13 (page 466)

Question: A chiral alkyne A with molecular formula C6H10 is reduced with and Lindlar catalyst to B having the R configuration at its stereogeniccentre. What are the structures of A and B?

Short Answer

Expert verified

Answer

Structure A

Structure B

Step by step solution

01

Stereogenic center

An atom is attached with four different groups such that its mirror image non-superimposable is known as a stereogenic center.

When any two group’s positions are exchanged, the molecule structure results in enantiomers (two isomers with R and S configuration).

02

Reaction of A with Lindlar catalyst

The triple bond is reduced to a double bond (cis alkene).

Reduction of alkyne to an alkene with stereogenic carbon center

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