Chapter 14: Q4P (page 527)
Question: How many \(^{\bf{1}}{\bf{H}}\) NMR signals does each dimethylcyclopropane show?
a.
b.
c.
Short Answer
- 2
- 3
- 3
Chapter 14: Q4P (page 527)
Question: How many \(^{\bf{1}}{\bf{H}}\) NMR signals does each dimethylcyclopropane show?
a.
b.
c.
All the tools & learning materials you need for study success - in one app.
Get started for freeQuestion: The \(^{\bf{1}}{\bf{H}}\) NMR spectrum 1,2-dimethoxyethane \(\left( {{\bf{C}}{{\bf{H}}_{\bf{3}}}{\bf{OC}}{{\bf{H}}_{\bf{2}}}{\bf{C}}{{\bf{H}}_{\bf{2}}}{\bf{OC}}{{\bf{H}}_{\bf{3}}}} \right)\) recorded on a 300 MHz NMR spectrometer consists of signals at 1017 Hz and 1065 Hz downfield from TMS. (a) Calculate the chemical shift of each absorption. (b) At what frequency would each absorption occur if the spectrum were recorded on a 500 MHz NMR spectrometer?
Draw all constitutional isomers of molecular formula C3H6Cl2.
a. How many signals does each isomer exhibit in its 1HNMR spectrum?
b.How many lines does each isomer exhibit in its 13CNMR spectrum?
c. When only the number of signals in both 1Hand 13C NMR spectroscopy is considered, is it possible to distinguish all of these constitutional isomers?
Question: Propose a structure consistent with each set of data.
a. A compound X (molecular formula C6H12O2) gives a strong peak in its IR spectrum at 1740 cm-1. The 1 H NMR spectrum of X shows only two singlets, including one at 3.5 ppm. The 13C NMR spectrum is given below Propose a structure for X.
b. A compound Y (molecular formula C6H10 ) gives four lines in its 13C NMR spectrum (27, 30, 67, and 93 ppm), and the IR spectrum given here. Propose a structure for Y.
Propose a structure consistent with each set of data.
a. C9H10O2: IR absorption at 1718cm-1
b. C9H12 : IR absorption at 2850โ3150cm-1
What do you think about this solution?
We value your feedback to improve our textbook solutions.