Chapter 14: Q.21558-14-27P. (page 557)
How many lines are observed in the 13C NMR spectrum of each compound?
a.
b.
c.
d.
Short Answer
a. Two lines
b. Four lines
c. Three lines
d. Four lines
Chapter 14: Q.21558-14-27P. (page 557)
How many lines are observed in the 13C NMR spectrum of each compound?
a.
b.
c.
d.
a. Two lines
b. Four lines
c. Three lines
d. Four lines
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Get started for freePropose a structure consistent with each set of data.
a. Compound J: molecular ion at 72; IR peak at 1710cm-1 ; 1H -NMR data (ppm) at 1.0 (triplet, 3 H), 2.1 (singlet, 3 H), and 2.4 (quartet, 2 H)
b. Compound K: molecular ion at 88; IR peak at 3600โ3200 ;1H-NMR data (ppm) at 0.9 (triplet, 3 H), 1.2 (singlet, 6 H), 1.5 (quartet, 2 H), and 1.6 (singlet, 1 H)
Draw all constitutional isomers of molecular formula \({{\bf{C}}_{\bf{3}}}{{\bf{H}}_{\bf{6}}}{\bf{C}}{{\bf{l}}_{\bf{2}}}\).
a. How many signals does each isomer exhibit in its \({}^{\bf{1}}{\bf{H}}\) NMR spectrum?
b. How many lines does each isomer exhibit in its \({}^{{\bf{13}}}{\bf{C}}\) NMR spectrum?
c. When only the number of signals in both \({}^{\bf{1}}{\bf{H}}\) and \({}^{{\bf{13}}}{\bf{C}}\) NMR spectroscopy is considered, is it possible to distinguish all of these constitutional isomers?
Esters of chrysanthemic acid are naturally occurring insecticides. How many lines are present in the NMR spectrum of chrysanthemic acid?
Question: Compound C has a molecular ion in its mass spectrum at 146 and a prominent absorption in its IR spectrum at 1762cm-1 . C shows the following 1H NMR spectral data: 1.47 (doublet, 3 H), 2.07 (singlet, 6 H), and 6.84 (quartet, 1 H) ppm. What is the structure of C?
Label each statement as True or False.
a. When a nucleus is strongly shielded, the effective field is larger than the applied field and the absorption shifts downfield.
b. When a nucleus is strongly shielded, the effective field is smaller than the applied field and the absorption is shifted upfield.
c. A nucleus that is strongly deshielded requires a lower field strength for resonance.
d. A nucleus that is strongly shielded absorbs at a larger ฮด value.
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