Chapter 14: Q.21558-14-27P. (page 557)
How many lines are observed in the 13C NMR spectrum of each compound?
a.
b.
c.
d.
Short Answer
a. Two lines
b. Four lines
c. Three lines
d. Four lines
Chapter 14: Q.21558-14-27P. (page 557)
How many lines are observed in the 13C NMR spectrum of each compound?
a.
b.
c.
d.
a. Two lines
b. Four lines
c. Three lines
d. Four lines
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Get started for freeQuestion: Using a 300 MHz NMR instrument:
a. How many Hz downfield from TMS is a signal at 2.5 ppm?
b. If a signal comes at 1200 Hz downfield from TMS, at what ppm does it occur?
c. If two signals are separated by 2 ppm, how many Hz does this correspond to?
Question: 18-Annulene shows two signals in its 1 H NMR spectrum, one at 8.9 (12 H) and one at โ1.8 (6 H) ppm. Using a similar argument to that offered for the chemical shift of benzene protons, explain why both shielded and deshielded values are observed for 18-annulene.
Question: Identify the carbon atoms that give rise to the signals in the 13C NMR spectrum of each compound.
a. CH3CH2CH2CH2OH ; 13CNMR: 14, 19, 35, and 62 ppm
b. (CH3)2CHCHO ; 13C NMR: 16, 41, and 205 ppm
c. CH2=CHCHOHCH3 ; 13C NMR: 23, 69, 113, and 143 ppm
Question. Compound O has a molecular formula C10H12O and shows an IR absorption at 1687 . The 1H -NMR spectrum of O is given below. What is the structure of O?
Question: Propose a structure consistent with each set of data.
a. A compound X (molecular formula C6H12O2) gives a strong peak in its IR spectrum at 1740 cm-1. The 1 H NMR spectrum of X shows only two singlets, including one at 3.5 ppm. The 13C NMR spectrum is given below Propose a structure for X.
b. A compound Y (molecular formula C6H10 ) gives four lines in its 13C NMR spectrum (27, 30, 67, and 93 ppm), and the IR spectrum given here. Propose a structure for Y.
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