Chapter 16: PROBLEM 16.40 (page 635)
Question: Rank the following dienes in order of increasing heat of hydrogenation.
Short Answer
Answer
Increasing order of heat of hydrogenation
Chapter 16: PROBLEM 16.40 (page 635)
Question: Rank the following dienes in order of increasing heat of hydrogenation.
Answer
Increasing order of heat of hydrogenation
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Get started for freeQuestion: Draw the product (A) of the following Diels-Alder reaction. A was a key intermediate in the synthesis of the addicting pain reliever morphine, the chapter-opening molecule.
Question: Label each pair of compounds as stereoisomers or conformations.
a.
b.
c.
Question: Label each product in the following reaction as a 1,2-product or 1,4-product, and decide which is the kinetic product and which is the thermodynamic product.
Question: Name each diene and state whether the ball-and-stick model shows the diene in the s-cis or s-trans conformation.
a.
b.
Question: Addition of HCl to alkene X forms two alkyl halides Y and Z.
a. Label Y and Z as a 1,2-addition product or a 1,4-addition product.
b. Label Y and Z as the kinetic or thermodynamic product and explain why.
c. Explain why addition of HCl occurs at the indicated C=C(called an exocyclic double bond), rather than the other C=C (called an endocyclic double bond).
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