Chapter 22: Q22. (page 898)
Question: How would you synthesize olestra from sucrose?
Short Answer
Answer
Synthesis of olestra
Chapter 22: Q22. (page 898)
Question: How would you synthesize olestra from sucrose?
Answer
Synthesis of olestra
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Get started for freeDraw the products formed when CH3COCH2CH2CH=CH2is treated with each reagent: (a)LiAlH4, then H2O ; (b) NaBH4in CH3OH ; (c) H2(1 equiv), Pd-C; (d)H2(excess), Pd-C; (e)NaBH4 (excess) inCH3OH ; (f) NaBD4in CH3OH
What Grignard reagent and carbonyl compound are needed to prepare each alcohol? As shown in part (d), 3o alcohols with three different R groups on the carbon bonded to the OH group can be prepared by three different Grignard reactions.
Question:Outline two different ways that butan-2-one can be prepared from a nitrile and a Grignard reagent.
Draw a stepwise mechanism for the following reaction. Your mechanism must show how both organic products are formed.
Question: What product is formed when acetic acid is treated with each reagent: (a) ; (b) , then heat; (c) + DCC?
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