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Question: Which of the following pairs of compounds can be separated from each other by an extraction procedure?

a.and

b.and

c. and NaCl

d. NaCl and KCl

Short Answer

Expert verified

Answer

a. The given pair of compounds can be separated by the extraction procedure.

b. The given pair of compounds cannot be separated by the extraction procedure.

c. The given pair of compounds can be separated by the extraction procedure.

d. The given pair of compounds cannot be separated by the extraction procedure.

Step by step solution

01

Step-by-Step SolutionStep 1: Extraction

A technique that is employed to segregate and purify various substances is extraction. Various solvents used for extraction include an organic solvent like dichloromethane and aqueous solvent like water.

02

Separation of compounds by extraction

A separatory funnel is utilized for the segregation of various substances in extraction.

The incorporation of two insoluble liquids into the separatory funnel leads to the formation of two layers. The less-dense layer is found on top, and a more dense layer is found on the bottom.

03

Compounds that can be separated by the extraction procedure

The compounds should have different solubility properties in order to separate them by extraction procedure.

a. The given pair of compounds can be separated by extraction procedure as the acid can be extracted to the aqueous base, and the alkene will stay in the organic layer.

b. These compounds cannot be separated as both compounds dissolve in organic solvents and are insoluble in water. Both the compounds are not acidic to be extracted to the aqueous base.

c. The given compounds can be separated, as one compound is a carboxylic acid and the other compound is a salt. The carboxylic acid can be dissolved in organic solvent and the salt can be dissolved in water.

d. The given compounds cannot be separated as both of them are salts. They dissolve in the water layer.

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Most popular questions from this chapter

ฮณ-Butyrolactone ( GBL) is a biologically inactive compound that is converted to the biologically active recreational drug GHB (Section 19.5) by a lactonase enzyme in the body. Since -butyrolactone is more fat-soluble than GHB, it is more readily absorbed by tissues and thus produces a faster onset of physiological symptoms. -Butyrolactone shows absorption in its IR spectrum at 1770 and the following NMR spectral data: 2.28 (multiplet, 2 H), 2.48 (triplet, 2 H), and 4.35 (triplet, 2 H) ppm. What is the structure of ฮณ-butyrolactone?

Explain why the pKaof compound A is lower than the pKaโ€™s of both compounds B and C.

Phthalic acid and isophthalic acid have protons on two carboxy groups that can be removed with base.

(a) Explain why the pKafor loss of the first proton (pKa1) is lower for phthalic acid than isophthalic acid.

(b) Explain why the pKafor loss of the second proton ( pKa2) is higher for phthalic acid than isophthalic acid.

Question: Give the IUPAC name for each compound.

a.

b.

c.

d.

e.

f.

: Identify each compound from its spectral data.

a. Molecular formula: C3H5ClO2

IR: 3500-2500 cm-1, 1714 cm-1

NMR data: 2.87 (triplet, 2 H), 3.76 (triplet, 2 H), and 11.8 (singlet, 1 H) ppm

b. Molecular formula: C8H8O3

IR: 3500-2500 cm-1, 1688cm-1

NMR data: 3.8 (singlet, 3 H), 7.0 (doublet, 2 H), 7.9 (doublet, 2 H), and 12.7 (singlet, 1 H) ppm

c. Molecular formula: C8H8O3

IR: 3500-2500 cm-1, 1710 cm-1

NMR data: 4.7 (singlet, 2 H), 6.9-7.3 ( multiplet, 5 H), and 11.3 (singlet, 1 H) ppm

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