Chapter 26: Q 13. (page 1063)
Draw the products formed when each alkene is treated with Grubbs catalyst.
a.
b.
c.
Short Answer
Answer
a.
b.
c.
Chapter 26: Q 13. (page 1063)
Draw the products formed when each alkene is treated with Grubbs catalyst.
a.
b.
c.
Answer
a.
b.
c.
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Get started for freeDraw the coupling product formed when each pair of compounds is treated with , , and .
Although diazomethane ( ) is often not a useful reagent for preparing cyclopropanes,other diazo compounds give good yields of more complex cyclopropanes. Draw a stepwisemechanism for the conversion of diazo compound A to B, an intermediate in the synthesis ofsirenin, the sperm attractant produced by the female gametes of the water mold Allomyces.
What ring-closing metathesis product is formed when each substrate is treated with Grubbs catalyst under high-dilution conditions?
a.
b.
c.
Devise a synthesis of each substituted cyclopropane. Use acetylene , as a startingmaterial in part (a), and cyclohexanone as a starting material in part (b). You may use anyother organic compounds and any needed reagents.
a.
b.
What product is formed by ring-closing metathesis of each compound?
a.
b.
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