Chapter 17: Q.41. (page 641)
Question: Draw a stepwise mechanism for the following reaction.
Short Answer
Answer
Chapter 17: Q.41. (page 641)
Question: Draw a stepwise mechanism for the following reaction.
Answer
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Get started for freeQuestion: Propose a structure consistent with each set of data.
a. Compound A:
Molecular formula:
IR absorption at role="math" localid="1648804967273"
NMR data: 1.4 (triplet, 3 H), 3.95 (quartet, 2 H), and 6.8โ7.3 (multiplet, 5 H) ppm
b. Compound B:
Molecular formula:
IR absorption at role="math" localid="1648805107903"
NMR data: 2.5 (singlet, 3 H), 3.8 (singlet, 3 H), 6.9 (doublet, 2 H), and 7.9 (doublet, 2 H) ppm
Question: Compound A exhibits a peak in its NMR spectrum at 7.6 ppm, indicating that it is aromatic.
(a) How are the carbon atoms of the triple bonds hybridized?
(b) In what type of orbitals are the electrons of the triple bonds contained?
(c) How many electrons are delocalized around the ring in A?
Question: How many electrons are contained in each molecule?
Question: Classify each compound as aromatic, antiaromatic, or not aromatic.
Question: Use the inscribed polygon method to show the pattern of molecular orbitals in cyclonona-1,3,5,7-tetraene and use it to label its cation, radical, and anion as aromatic, antiaromatic, or not aromatic.
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