Chapter 29: Q9. (page 1159)
Draw the products of each reaction.
(a)
(b)
(c)
(d)
Short Answer
(a)
(b)
(c)
(d)
Chapter 29: Q9. (page 1159)
Draw the products of each reaction.
(a)
(b)
(c)
(d)
(a)
(b)
(c)
(d)
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Get started for freeQuestion: Identify A and B, isomers of molecular formula \({{\bf{C}}_{\bf{3}}}{{\bf{H}}_{\bf{4}}}{\bf{C}}{{\bf{l}}_{\bf{2}}}\), from the given \({}^{\bf{1}}{\bf{H}}\)NMR data: Compound A exhibits signals at 1.75 (doublet, 3H,\({\bf{J = 6}}{\bf{.9 Hz}}\)) and 5.89 (quartet, \({}^{\bf{1}}{\bf{H}}\),\({\bf{J = 6}}{\bf{.9 Hz}}\)) ppm. Compound B exhibits signals at 4.16 (singlet, 2 H), 5.42 (doublet, \({}^{\bf{1}}{\bf{H}}\),\({\bf{J = 1}}{\bf{.9 Hz}}\)), and 5.59 (doublet, \({}^{\bf{1}}{\bf{H}}\), \({\bf{J = 1}}{\bf{.9 Hz}}\)) ppm.
Devise a synthesis of each amino acid from acetaldehyde :
(a) Glycine;
(b) Alanine.
Devise a stepwise synthesis of the tripeptide Val-leu-Val from 3-methylbutanal as the only organic starting material. You may also use any required inorganic or organic reagents.
What is the predominant form of each of the following amino acids at pH=11? What is the overall charge on the amino acid? (a)valine; (b)proline; (c)glutamic acid; (d)lysine?
Which of the following amines can be used to resolve a racemic mixture of amino acids?
(a)
(b)
(c)
(d)
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