Chapter 29: Q49. (page 1194)
Draw the organic products formed in each reaction
Chapter 29: Q49. (page 1194)
Draw the organic products formed in each reaction
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Get started for freeGive the amino acid sequence of an octapeptide that contains the amino acids Tyr, Ala, Leu (2 equiv), Cys, Gly, Glu and Val, and forms the following fragments when partially hydrolyzed with HCl: Val-Cys-Gly-Glu, Ala-Leu-Tyr, and Tyr-Leu-Val-Cys.
Draw the mechanism for the reaction that removes an Fmoc group from an amino acid under the following conditions:
Draw the structure of each peptide. Label the N-terminal and C-terminal amino acids and all amide bonds.
a. ValโGlu
b. GlyโHisโLeu
c. MโAโTโT
As shown in Mechanism 29.2, the final steps in the Edman degradation result in rearrangement of a thiazolinone to an N-phenylthiohydantoin. Draw a stepwise mechanism for this acid-catalyzed reaction.
Question: Identify the nucleophile and the electrophile in the following acidโbase reactions:
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