Chapter 29: Q4. (page 1156)
L-thyroxine, a thyroid hormone and oral medication used to treat thyroid hormone deficiency, is an amino acid that does not exist in proteins. Draw the zwitterionic form of L-thyroxine.
Chapter 29: Q4. (page 1156)
L-thyroxine, a thyroid hormone and oral medication used to treat thyroid hormone deficiency, is an amino acid that does not exist in proteins. Draw the zwitterionic form of L-thyroxine.
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Get started for freeThe enolate derived from diethyl acetamidomalonate is treated with each of the following alkyl halides. After hydrolysis and decarboxylation, what amino acid is formed?
What aldehyde is needed to synthesize each amino acid by the Strecker synthesis?
(a) Valine;
(b) Leucine;
(c) Phenylalanine.
Glutathione, a powerful antioxidant that destroys harmful oxidizing agents in cells, is composed of glutamic acid, cysteine, and glycine, and has the following structure:
Glutathione
a. What product is formed when glutathione reacts with an oxidizing agent?
b. What is unusual about the peptide bond between glutamic acid and cysteine?
Draw the structure for each peptide:
(a) PheโAla;
(b) GlyโGln;
(c) LysโGly;
(d) R-H
What alkene is needed to synthesize each amino acid by an enantioselective hydrogenation reaction using and :
(a) Alanine;
(b) Leucine;
(c) Glutamine?
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