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Chapter 25: PROBLEM 25.29 (page 1029)

Question: Draw the product formed when each compound is treated with NaNO2 and HCl.

a.

b.

c.

d.


Short Answer

Expert verified

Answer

a.

b.

c.

d.

Step by step solution

01

Diazotization reaction

The diazotization reaction occurs between an amine and NaNO2 , HCl. The reagent gives the nitrous acid, which the amine substrate attacks to form products.

02

Reaction of primary, secondary amine

  • The primary amine on the reaction with NaNO2 and HCl gives a salt.
  • The secondary amine on the reaction with NaNO2 and HCl gives a nitrosoamine product.
03

Explanation

a. The given amine is a primary amine which gives the product as:

Product formation from a.

b. The given amine is a secondary amine which gives the product as:

Product formation from b.

c. The given amine is a secondary amine which gives the product as:

Product formation from c.

d. The given amine is a primary amine which gives the product as:

Product formation from d.

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