Chapter 7: PROBLEM 7.2 (page 250)
Give the IUPAC name for each compound
a)
b)
c)
d)
Short Answer
- 3-chloro-2-methylpentane
- 2-bromo-5,5-dimethylheptane
- 1-bromo-2-methylcyclohexane
- 6-ethyl-2-fluoro-7-isopropyldecane
Chapter 7: PROBLEM 7.2 (page 250)
Give the IUPAC name for each compound
a)
b)
c)
d)
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Get started for freeQuestion: Does the equilibrium favor the reactants or products in each substitution reaction?
a.
b.
Telfairine, a naturally occurring insecticide, and halomon, an antitumor agent, are two polyhalogenated compounds isolated from red algae. (a) Classify each halide bonded to an sp3 hybridized carbon as 1°, 2°, or 3°. (b) Label each halide as vinyl, allylic, or neither.
Question: For each reaction, use the identity of the alkyl halide and nucleophile to determine which substitution mechanism occurs. Then determine which solvent affords the faster reaction
a.
b.
c.
Question: You will often return to nucleophilic substitution, in particular the SN2 reaction, in subsequent chapters and concentrate on the nucleophile rather than the alkyl halide. By using different nucleophiles, nucleophilic substitution allows the synthesis of a wide variety of organic compounds with many different functional groups. With this in mind, draw the products of each two-step sequence. (Hint: Step [1] in each part involves an acid-base reaction that removes the most acidic hydrogen from the starting material.)
a.
b.
c.
Question: Draw the structure of a , , carbocation, each having molecular formula . Rank the three carbocations in order of increasing stability.
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