Chapter 10: Q.34. (page 420)
Question: Name the alkene depicted in the ball-and-stick model and draw the constitutional isomers formed when the alkene is treated with each reagent: (a) ; (b) in ; (c) in .
Short Answer
Answer
Chapter 10: Q.34. (page 420)
Question: Name the alkene depicted in the ball-and-stick model and draw the constitutional isomers formed when the alkene is treated with each reagent: (a) ; (b) in ; (c) in .
Answer
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Question: Like other electrophiles, carbocations add to alkenes to form new carbocations, which can then undergo substitution or elimination reactions depending on the reaction conditions. With this in mind, consider the following reactions of nerol, a natural product isolated from lemon grass and other plant sources. Treatment of nerol with TsOH forms ฮฑ-terpineol as the major product, whereas treatment of nerol with chlorosulfonic acid, HSO3Cl , forms a constitutional isomer, ฮฑ-cyclogeraniol. Write stepwise mechanisms for both processes. Each mechanism involves the addition of an electrophileโa carbocationโ to a double bond.
Question: Draw the constitutional isomer formed in each reaction.
a.
b.
c.
d.
e.
f.
Question: Label each C-C double bond as E or Z. Kavain is a naturally occurring relaxant isolated from kava root.
Question: How many degrees of unsaturation does each of the following drugs contain?
a.โ zolpidem (sleep aid sold as Ambien),
b.โ mefloquine (antimalarial drug),
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