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Chapter 30: Question 30.49 (page 1228)

Draw the products of each reaction.

(a.)

(b.)

(c.)

(d.)

(e.)

(f.)

(g.)

(h.)

Short Answer

Expert verified

Answer

(a.First polymer

(b.)Second polymer

(c.)Third polymer

(d.)Fourth polymer

(e.)Fifth polymer

(f.)Sixth compound

(g.)Seventh polymer

(h.)Eighth polymer

Step by step solution

01

Reaction of 1-methoxy-4-vinylbenzene with 2-(tert-butylperoxy)-2-methylpropane

In this reaction, the double bond present outside the benzene ring opens and forms repeating units. The methoxy functional group remains unchanged. The reaction is shown below.

Reaction of 1-methoxy-4-vinylbenzene with 2-(tert-butylperoxy)-2-methylpropane

02

Reaction of 2-methylpent-1-en-3-one with butyl lithium

This reaction will lead to the conversion of the double bond to a single bond.The monomer units keep on repeating to form a giant polymer molecule. The reaction is shown below.

Reaction of 2-methylpent-1-en-3-one with butyl lithium

03

Reaction of 2-methylbut-1-ene with boron trifluoride and water

This reaction will lead to the conversion of the double bond to a single bond. The monomer units keep on repeating to form a giant polymer molecule. The reaction is shown below.

Reaction of 2-methylbut-1-ene with boron trifluoride and water

04

Reaction of 2-cyclohexyl-2-methyloxiranewith hydroxide ion

This reaction will lead to opening of epoxide ring. Themonomers connect to each other through an oxygen atom. The monomer units keep on repeating to form a giant polymer molecule. The reaction is shown below.

Reaction of 2-cyclohexyl-2-methyloxirane with hydroxide ion

05

Reaction of resorcinol with 2-(chloromethyl)oxirane

This reaction will lead to opening of epoxide ring. The monomers connect to each other though oxygen atom. The monomer units keep on repeating to form a giant polymer molecule. The reaction is shown below.

Reaction of resorcinol with 2-(chloromethyl)oxirane

06

Reaction of water and hydroxide ion with the given polymer

This reaction will lead to the formation of two products. One is butane-1,4-diol and the other is terephthalate. The reaction is shown below.

Reaction of water and hydroxide ion with the given polymer

07

Reaction of 1,4-diisocyanatobenzene andcyclohexane-1,4-diol

This reaction will lead to the formation of a polymer in which the monomer units are connected by oxygen atom. The reaction is shown below.

Reaction of 1,4-diisocyanatobenzene and cyclohexane-1,4-diol

08

Reaction of butane-1,4-diol and phosgene

This reaction will lead to the formation of a polymer in which the monomer units are connected by an oxygen atom. The reaction is shown below.

Reaction of butane-1,4-diol and phosgene

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