Chapter 30: Question 30.3 (page 1202)
What polymer is formed by the radical polymerization of each monomer?
(a.)
(b.)
Short Answer
Answer
(a.)
(b.)
Chapter 30: Question 30.3 (page 1202)
What polymer is formed by the radical polymerization of each monomer?
(a.)
(b.)
Answer
(a.)
(b.)
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Get started for freeDraw a stepwise mechanism for the anionic polymerization of styrene to form polystyrene using BuLi as an initiator. Use CO2 as the electrophile that terminates the chain mechanism.
Draw a stepwise mechanism for the reaction of an alcohol with an isocyanate to form a urethane.
Although chain branching in radical polymerizations can occur by intermolecular H abstraction as shown in Mechanism 30.2, chain branching can also occur by intramolecular H abstraction to form branched polyethylene that contains butyl groups as branches.
a. Draw a stepwise mechanism that illustrates which H must be intramolecularly abstracted to form butyl substituents.
b. Suggest a reason why the abstraction of this H is more facile than the abstraction of other Hโs.
Lexan can also be prepared by the acid-catalyzed reaction of diphenyl carbonate with bisphenol A. Draw a stepwise mechanism for this process.
What epoxy resin is formed by the following reaction sequence?
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