Chapter 27: Q 51. (page 1103)
Question: Draw the product formed (including stereochemistry) in each pericyclic reaction.
Short Answer
Answer
Product of b
Chapter 27: Q 51. (page 1103)
Question: Draw the product formed (including stereochemistry) in each pericyclic reaction.
Answer
Product of b
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Get started for freeQuestion:Draw a stepwise mechanism for the Carroll rearrangement, a reaction that prepares aฮณ,ฮด-unsaturated carbonyl compound from aฮฒ-keto ester and allylic alcohol in the presence ofbase.
Question: What product is formed by [3,3] sigmatropic rearrangement of the following compound? Clearly indicate the stereochemistry around all tetrahedral stereogenic centers.
Question: Draw the product of each electrocyclic reaction.
a. the thermal electrocyclic ring closure of (2E,4Z,6Z)-nona-2,4,6-triene
b. the photochemical electrocyclic ring closure of (2E,4Z,6Z)-nona-2,4,6-triene
c. the thermal electrocyclic ring-opening of cis-5-ethyl-6-methylcyclohexa-1,3-diene
d. the photochemical electrocyclic ring-opening of trans-5-ethyl-6-methylcyclohexa-1,3- diene
Question: a) What is the structure of C, which is formed by oxy-Cope rearrangement of B with NaOEt?
(b) Draw a stepwise mechanism for the conversion of C to the bicyclic alcohol D.
Question: Use curved arrows to show how E is converted to F by a two-step reaction sequence consisting of a [1,5] sigmatropic rearrangement followed by a [4 + 2] cycloaddition.
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