Chapter 27: Q 47. (page 1102)
Question: What product is formed from the sigmatropic rearrangement of the following unsaturated ether?
Short Answer
Answer
Chapter 27: Q 47. (page 1102)
Question: What product is formed from the sigmatropic rearrangement of the following unsaturated ether?
Answer
All the tools & learning materials you need for study success - in one app.
Get started for freeQuestion: (a) How many π molecular orbitals are present in deca-1,3,5,7,9-pentaene ? (b) How many are bonding MOs and how many are antibonding MOs ? (c) How many nodes are present in ? (d) How many nodes are present in ?
Question: Draw the product formed when each triene undergoes electrocyclic reaction under [1] thermal conditions, [2] photochemical conditions
Question: Using the Woodward–Hoffmann rules in Table 27.4, predict the stereochemistry of each reaction.
a. a [6 + 4] thermal cycloaddition
b. photochemical electrocyclic ring closure of deca-1,3,5,7,9-pentaene
c. a [4 + 4] photochemical cycloaddition
d. a thermal [5,5] sigmatropic rearrangement
Question:Consider cycloheptatrienone and ethylene, and draw a possible product formed from each type of cycloaddition:
(a) [2 + 2]
(b) [4 + 2]
(c) [6 + 2]
Question: For each molecular orbital in Figure 27.2, count the number of bonding interactions (interactions between adjacent orbitals of similar phase) and the number of nodes. (a) How do these two values compare for a bonding molecular orbital? (b) How do these two values compare for an antibonding molecular orbital?
What do you think about this solution?
We value your feedback to improve our textbook solutions.