Chapter 27: Q 47. (page 1102)
Question: What product is formed from the sigmatropic rearrangement of the following unsaturated ether?
Short Answer
Answer
Chapter 27: Q 47. (page 1102)
Question: What product is formed from the sigmatropic rearrangement of the following unsaturated ether?
Answer
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Get started for freeQuestion: Classify each pericyclic reaction as an electrocyclic reaction, cycloaddition, or sigmatropic rearrangement. Indicate whether the stereochemistry is conrotatory, disrotatory, suprafacial, or antarafacial.
Question:What starting materials are needed to synthesize each compound by a thermal [4 + 2] cycloaddition?
Question: Draw the product of the [3,3] sigmatropic rearrangement of each compound.
Question: What type of sigmatropic rearrangement is illustrated in each reaction?
Question: What product is formed when each compound undergoes thermal electrocyclic ring-opening or ring closure? Label each process as conrotatory or disrotatory and clearly indicate the stereochemistry around tetrahedral stereogenic centers and double bonds.
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