Chapter 31: Question 31.6 (page 1239)
Draw the structure of a lecithin containing oleic acid and palmitic acid as the fatty acid side chains.
Short Answer
Answer
Chapter 31: Question 31.6 (page 1239)
Draw the structure of a lecithin containing oleic acid and palmitic acid as the fatty acid side chains.
Answer
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Get started for freeTriacylglycerol L yields compound M when treated with excess H2 , Pd-C. Ozonolysis of L [1] O3 ; [2] affords compounds N-P. What is the structure of L?
Farnesyl diphosphate is cyclized to sesquiterpene A, which is then converted to the bicyclic product epi-aristolochene. Write a stepwise mechanism for both reactions.
Draw the structure of the following phospholipids:
a. a cephalin formed from two molecules of stearic acid
b. a sphingomyelin formed from palmitic acid.
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A difficult problem in the synthesis of PGFis the introduction of the OH group at C15 in the desired configuration.
A well known synthesis of PGFinvolves reaction of A with (a metal hydride reagent similar in reactivity to, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship.
Suggest a reagent to convert A to the single stereoisomer X.
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