Chapter 31: Q20P (page 1250)
One component of lanolin, the wax that coats sheep’s wool, is derived from cholesterol and stearic acid. Draw its structure, including the correct stereochemistry of all stereogenic centers.
Short Answer
Answer
Chapter 31: Q20P (page 1250)
One component of lanolin, the wax that coats sheep’s wool, is derived from cholesterol and stearic acid. Draw its structure, including the correct stereochemistry of all stereogenic centers.
Answer
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Get started for freeExplain why regularly ingesting a large excess of a fat-soluble vitamin can lead to severe health problems, whereas ingesting a large excess of a water-soluble vitamin often causes no major health problems.
Locate the isoprene units in each compound.
a
b.
Crocin, which occurs naturally in crocus and gardenia flowers, is primarily responsible for the color of saffron.
(a) What lipid and monosaccharides are formed by the hydrolysis of crocin?
(b) Classify the lipid as a monoterpenoid, diperpenoid, etc., and locate the isoprene units.
Flexibilene is a terpene isolated from Sinulariaflexibilis, a soft coral found in the Indian Ocean. Draw a stepwise mechanism for the formation of flexibilene from farnesyl diphosphate and isopentenyl diphosphate. What is unusual about the cyclization that forms the 15-membered ring of flexibilene?
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