Chapter 28: Question 28.37 (page 1147)
Convert each ball-and-stick model to a Fischer projection.
(a.)
(b.)
Short Answer
Answer
(a.) Fischer Projection formula of compound a.
(b.) Fischer Projection formula of compound b.
Chapter 28: Question 28.37 (page 1147)
Convert each ball-and-stick model to a Fischer projection.
(a.)
(b.)
Answer
(a.) Fischer Projection formula of compound a.
(b.) Fischer Projection formula of compound b.
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Get started for freeDrawthe structure of:
(a) a polysaccharide formed by joining d-mannose units in -glycosidic linkages;
(b) a polysaccharide formed by joining d-glucose units in -glycosidic linkages.
The polysaccharide in (b) is dextran, a component of dental plaque.
The most stable conformation of the pyranose ring of most D-aldohexoses places the largest group, CH2OH, in the equatorial position. An exception to this is the aldohexose D-idose. Draw the two possible chair conformations of either the anomers of D-idose. Explain why the more stable conformation has the CH2OH group in the axial position.
A D-aldohexose A is formed from an aldopentose B by the Kiliani-Fischer synthesis. Reduction of A with forms an optically inactive alditol. Oxidation of B forms an optically active aldaric acid. What are the structures of A and B?
Convert each cyclic monosaccharide into its acyclic form.
(a.)
(b.)
(c.)
(d.)
Draw a Haworth projection for each compound using the structures in Figures 28.4 and 28.5.
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