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Chapter 29: Q12P (page 1163)

Draw the organic products formed in the following reaction.

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01

Chemical reaction

Chemical reaction is a reaction where reactants are reacted and desired products are formed.Chemical reaction can be carried out in both organic and inorganic compounds. It depends upon catalyst, temperature, and reactant.

02

Reagent’s role

Acetic anhydride is used for acetylation, manufacturing cigarette filters, and wood preservative.

03

Reaction

When the mixture of enantiomers of leucine is treated with (CH3CO)2 O and acylaseN-acetyl-(S)-leucine and N-acetyl-(R)-leucine are formed.

Formation of (S)-leucine and (R)-leucine

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Most popular questions from this chapter

The anti-obesity drug orlistat works by irreversibly inhibiting pancreatic lipase, an enzyme responsible for the hydrolysis of triacylglycerols in the intestines, so they are excreted without metabolism, inhibition occurs by reaction of orlistat with a serine residue of the enzyme, forming a covalently bound, inactive enzyme product. Draw the structure of the product formed during inhibition.

Draw the products of each reaction.

(a)

(b)

(c)

(d)

Draw the product formed when the following amino acid is treated with each reagent: (a)CH3OH;H+; (b)CH3COCl, pyridine; (c) HCl (1 equiv); (d) NaOH (1 equiv); (e)C6H5N=C=S.

What alkyl halide is needed to synthesize each amino acid from diethyl acetamidomalonate: (a)Asn; (b)His; (c)Trp?

What form exists at the isoelectric point of each of the following amino acids: (a) valine; (b)leucine; (c)proline; (d) glutamic acid
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