Chapter 21: 51P (page 817)
What hydrolysis products are formed when the following compound is treated with aqueous acid?
Chapter 21: 51P (page 817)
What hydrolysis products are formed when the following compound is treated with aqueous acid?
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Get started for freeDraw a stepwise mechanism for the following imine hydrolysis
Etoposide, sold as a phosphate derivative with the trade name of Etopophos, is used for the treatment of lung cancer, testicular cancer, and lymphomas. (a) Locate the acetals in etoposide. (b) What products are formed when all of the acetals are hydrolyzed with aqueous acid?
DrawโtheโproductโformedโwhenโCH3CH2CH2CH2NH2reacts with each carbonyl compound in the presence of mild acid.
a.
b.
c.
Maltose is a carbohydrate present in malt, the liquid obtained from barley and other grains. Although maltose has numerous functional groups, its reactions are explained by the same principles we have already encountered.
a. Label the acetal and hemiacetal carbons.b. What products are formed when maltose is treated with each of the following reagents: [1] ; [2] and HCl; [3] excess NaH, then excess ?c. Draw the products formed when the compound formed in Reaction [3] of part (b) is treated with aqueous acid.The reactions in parts (b) and (c) are used to determine structural features of carbohydrates like maltose. We will learn much more about maltose and similar carbohydrates in Chapter 28.
An unknown compound D exhibits a strong absorption in its IR spectrum at 1692 cm-1 . The mass spectrum of D shows a molecular ion at m/z = 150 and a base peak at 121. The 1H- NMR spectrum of D is shown below. What is the structure of D?
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