Chapter 21: 4P (page 817)
Give the IUPAC name for each aldehyde.
a.2-isobutyl-3-isopropylhexanal
b. trans-3-methylcyclopentanecarbaldehyde
c. 1-methylcyclopropanecarbaldehyde
d. 3,6-diethylnonanal
Short Answer
a.
b
c
d
Chapter 21: 4P (page 817)
Give the IUPAC name for each aldehyde.
a.2-isobutyl-3-isopropylhexanal
b. trans-3-methylcyclopentanecarbaldehyde
c. 1-methylcyclopropanecarbaldehyde
d. 3,6-diethylnonanal
a.
b
c
d
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Get started for freeReaction of 5,5-dimethoxypentan-2-one with methylmagnesium iodide followed by treatment with aqueous acid forms cyclic hemiacetal Y. Draw a stepwise mechanism that illustrates how Y is formed
Draw all stereoisomers formed in each reaction.
a.
b.
c.
d.
A solution of acetone (CH3)2C=O in ethanol CH3CH2OH in the presence of a trace of acid was allowed to stand for several days, and a new compound of molecular formula C7H16O2 was formed. The IR spectrum showed only one major peak in the functional group region around 3000 cm-1 , and the 1H-NMR spectrum is given here. What is the structure of the product?
Two naturally occurring compounds that contain stable cyclic hemiacetals and acetals are monensin and digoxin, the chapter-opening molecule. Monensin, a polyether antibiotic produced by Streptomyces cinamonensis,is used as an additive in cattle feed. Digoxin is a widely prescribedcardiac drug used to increase the force of heart contractions. Label each acetal, hemiacetal, and ether in both compounds.
Show two methods to synthesize each alkene: a one-step method using a Wittig reagent, and a two-step method that forms a carbon–carbon bond with an organometallic reagent in one of the steps.
a.
b.
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