Chapter 21: 1P (page 817)
Rank the following compounds in order of increasing reactivity towards nucleophilic attack.
Chapter 21: 1P (page 817)
Rank the following compounds in order of increasing reactivity towards nucleophilic attack.
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Get started for freeTreatment of (HOCH2CH2CH2CH2)2CO with acid forms a product of molecular formula C9H16O2and a molecule of water. Draw the structure of the product and explain howit is formed.
The boiling point of butan-2-one ( 79.64oC ) is significantly higher than the boiling point of diethyl ether ( 34.6OC), even though both compounds exhibit dipoleโdipole interactions and have comparable molecular weights. Offer an explanation.
Consider the para-substituted aromatic ketones, NO2C6H4COCH2 (p-nitroacetophenone) and CH3OC6H4COCH3 (p-methoxyacetophenone).
a. Which carbonyl compound is more stable?
b. Which compound forms the higher percentage of hydrate at equilibrium?
c. Which compound exhibits a carbonyl absorption at a higher wavenumber in its IR spectrum?
Explain your reasoning in each part.
Draw a stepwise mechanism for the following reaction
Draw the products of each reaction.
a.
b.
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