Chapter 21: 16P (page 817)
What cyanohydrin and carbonyl compound are formed when amygdalin is metabolized in a similar manner to linamarin?
Short Answer
The compounds are mentioned below:
Chapter 21: 16P (page 817)
What cyanohydrin and carbonyl compound are formed when amygdalin is metabolized in a similar manner to linamarin?
The compounds are mentioned below:
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Draw a stepwise mechanism for the following reaction, a key step in the synthesis of the anti-inflammatory drug celecoxib (trade name Celebrex).
Consider the para-substituted aromatic ketones, NO2C6H4COCH2 (p-nitroacetophenone) and CH3OC6H4COCH3 (p-methoxyacetophenone).
a. Which carbonyl compound is more stable?
b. Which compound forms the higher percentage of hydrate at equilibrium?
c. Which compound exhibits a carbonyl absorption at a higher wavenumber in its IR spectrum?
Explain your reasoning in each part.
Draw a stepwise mechanism for the following reaction
What carbonyl compound and alcohol are formed by hydrolysis of each acetal?
a.
b.
c.
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