Chapter 21: 14P (page 817)
Draw the products of each reaction. Include all stereoisomers formed
a.
b.
Short Answer
a.
b.
Chapter 21: 14P (page 817)
Draw the products of each reaction. Include all stereoisomers formed
a.
b.
a.
b.
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Get started for freeDraw a stepwise mechanism for the following reaction, a key step in the synthesis of the anti-inflammatory drug celecoxib (trade name Celebrex).
Draw the products (including stereoisomers) formed when benzaldehyde (C6H5CHO) is treated with each Wittig reagent
a.
b.
What carbonyl compound and amine or alcohol are needed to prepare each product?
a.
b.
c.
d.
-d-Glucose, a hemiacetal, can be converted to a mixture of acetals on treatment with in the presence of acid. Draw a stepwise mechanism for this reaction. Explain why two acetals are formed from a single starting material.
Safrole is a naturally occurring acetal isolated from sassafras plants. Once used as a common food additive in root beer and other beverages, it is now banned because it is carcinogenic. What compounds are formed when safrole is hydrolysed with aqueous acid?
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