Chapter 21: 13P (page 817)
What alkene would yield 2,2-dimethoxycyclopentane-1,3-dicarbaldehyde on treatment withfollowed by ?
Chapter 21: 13P (page 817)
What alkene would yield 2,2-dimethoxycyclopentane-1,3-dicarbaldehyde on treatment withfollowed by ?
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Get started for freeWhat Wittig reagent and carbonyl compound are needed to prepare each alkene? When two routes are possible, indicate which route, if any, is preferred.
a.
b.
c.
a. How many stereogenic centers are present in -D-galactose?
b. Label the hemiacetal carbon in -D-galactose.
c. Draw the structure of -D-galactose.
d. Draw the structure of the polyhydroxy aldehyde that cyclizes to - and
-D-galactose.
e. From what you learned in Section 21.16B, what product (s) is (are) formed
when -D-galactose is treated with CH3OH and an acid catalyst?
What products are formed when each acetal is hydrolyzed with aqueous acid?
a.
b.
Give the structure corresponding to each name.
a. 2-methyl-3-phenylbutanal
b. 3,3-dimethylcyclohexanecarbaldehyde
c. 3-benzoylcyclopentanone
d. 2-formylcyclopentanone
e. (R)-3-methylheptan-2-one
f. m-acetylbenzaldehyde
g. 2-sec-butylcyclopent-3-enone
h. 5,6-dimethylcyclohex-1-enecarbaldehyde
Draw a stepwise mechanism for the following reaction
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