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A greenish yellow gas reacts with an alkali metal hydroxide to form a halate which can be used in fire works and safety matches. The gas and halate respectively are: (a) \(\mathrm{Br}_{2}, \mathrm{KBrO}_{3}\) (b) \(\mathrm{Cl}_{2}, \mathrm{KClO}_{3}\) (c) \(\mathrm{I}_{2}, \mathrm{NaIO}_{3}\) (d) \(\mathrm{Cl}_{2}, \mathrm{NaClO}_{3}\)

Short Answer

Expert verified
The correct answer is (b) \( \mathrm{Cl}_2, \mathrm{KClO}_3 \).

Step by step solution

01

Identify the Greenish Yellow Gas

The description mentions a greenish yellow gas. Chlorine gas (\( \mathrm{Cl}_2 \)) is known for its greenish yellow color. Therefore, the gas in question is most likely chlorine.
02

Understand the Reaction with Alkali Metal Hydroxide

When chlorine (\( \mathrm{Cl}_2 \)) reacts with an alkali metal hydroxide (\( \mathrm{NaOH} \) or \( \mathrm{KOH} \)), it can form a halate. This reaction usually forms a chlorate (\( \mathrm{ClO}_3^- \)) ion as a product, which is part of compounds like \( \mathrm{KClO}_{3} \) or \( \mathrm{NaClO}_{3} \).
03

Identify the Halate Used in Fireworks and Matches

Chlorates, such as potassium chlorate (\( \mathrm{KClO}_3 \)) or sodium chlorate (\( \mathrm{NaClO}_3 \)), are known to be used in fireworks and safety matches due to their ability to produce oxygen and enhance combustion.
04

Match the Gas and Halate to the Options

From the description provided, \( \mathrm{Cl}_2 \) and \( \mathrm{KClO}_3 \) seems to fit the criteria of a greenish yellow gas forming a halate usable in fireworks and matches. Option (b) matches this description.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chlorine gas
Chlorine gas, represented chemically as \( \mathrm{Cl}_2 \), is a highly recognizable compound due to its distinct greenish-yellow color. This gaseous element is part of the halogen group in the periodic table, identified as highly reactive. Its reactivity owes to its desire to gain an electron to achieve a stable octet configuration.
Chlorine gas is widely used in various industries for multiple applications, such as water purification, disinfection, and the production of essential chemicals. However, it is crucial to handle chlorine gas with care, as it is toxic and can cause harm if inhaled or improperly managed.
Halates
Halates are a group of chemical compounds comprised of halogen atoms bonded to oxygen in a specific arrangement. In these compounds, the central halogen atom is bonded to oxygen resulting in polyatomic ions like chlorates (\( \mathrm{ClO}_3^- \)), bromates, and iodates.
These compounds are useful in various chemical reactions, especially those requiring an oxidizing agent. Halates are often employed in processes to clean, bleach, and disinfect due to their ability to release oxygen, thus facilitating oxidation reactions. Their composition and properties make them valuable in both industrial and laboratory settings.
Fireworks chemistry
Fireworks rely heavily on specific chemical reactions, most notably those involving oxidizing agents like chlorates. When a firework is set off, the oxidizing agents break down to release oxygen. This oxygen is crucial for the combustion of the fuel components within the firework, leading to the explosive display we observe.
Chlorate compounds, such as potassium chlorate (\( \mathrm{KClO}_3 \)), are favored for this purpose because they efficiently break down to release oxygen, which accelerates the burning of the firework components. Additionally, mixing chlorates with metal salts can produce a wide array of colors, adding to the visual spectacle.
Safety matches
Safety matches are an everyday application of halates, particularly chlorates. These matches utilize the chemical properties of chlorates to ignite. Usually, potassium chlorate (\( \mathrm{KClO}_3 \)) is incorporated into the match head.
The head also contains a fuel source, typically sulfur, and upon striking, friction heats the mixture causing it to ignite. The oxygen released from the decomposition of potassium chlorate accelerates this process, ensuring a reliable flame. Safety matches are specifically designed to ignite only when struck on a matchbox, promoting controlled and safe use.
Chlorate formation
The formation of chlorates, such as sodium chlorate (\( \mathrm{NaClO}_3 \)) or potassium chlorate (\( \mathrm{KClO}_3 \)), involves the reaction of chlorine gas with an alkali metal hydroxide, like sodium hydroxide (\( \mathrm{NaOH} \)) or potassium hydroxide (\( \mathrm{KOH} \)).
During this chemical reaction, chlorine reacts with the hydroxide, leading to the formation of chlorate ions \( (\mathrm{ClO}_3^-) \). The balanced reaction typically entails intermediate formations, such as hypochlorites, before finally yielding the stable chlorate ion. This process highlights the interplay of chemical reactivity and formation of useful compounds for a variety of purposes, from industry to pyrotechnics.

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