Chapter 6: Problem 14
Energy can be transferred from a system to its surroundings as work if (1) there is thermal equilibrium between system and surroundings (2) there is mechanical equilibrium between system and surroundings (3) if pressure of system \(>\) atmospheric pressure (4) if pressure of system \(<\) atmospheric pressure
Short Answer
Step by step solution
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
thermal equilibrium
When we discuss energy transfer, especially in terms of work, thermal equilibrium means any heat energy exchange is non-existent. This is important in thermodynamics because it helps define conditions where only mechanical energy (work) can be transferred without the interference of thermal energy.
Hence, for work energy transfer focusing solely on mechanical interactions, the system and surroundings must either ignore or have already achieved thermal equilibrium.
mechanical equilibrium
In the context of energy transfer as work, mechanical equilibrium is significant because it creates a condition where there are no driving forces to perform work. To transfer energy as work, there must be an imbalance – pressure differences or unbalanced forces. If the system and surroundings are in mechanical balance, no work can be performed due to a lack of force differences.
pressure differences
If the pressure inside a system is greater than the atmospheric pressure (outside), the system can expand, doing work on the surroundings. Conversely, if the system's pressure is less than the atmospheric pressure, the surroundings can do work on the system, compressing it.
This is crucial for understanding how energy can be transferred: without a pressure difference, no work can be done. Thus, for work transfer, the system's pressure must either exceed or be less than the external pressure – maintaining equality (mechanical equilibrium) would prevent any work energy transfer.
work transfer
To facilitate work transfer, two essential conditions are:
- There must be a pressure difference between the system and surroundings. This pressure difference provides the necessary force.
- Either the system performs work on the surroundings (when its pressure is higher) or the surroundings perform work on the system (when its pressure is lower).
In summary, pressure differences drive the capability to transfer energy as work, making it a pivotal concept in thermodynamic study.