Question

The electronic configuration of the element which is just above the element with atomic number 43 in the same group is (1) \(1 \mathrm{~s}^{2} 2 \mathrm{~s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{~s}^{2} 3 \mathrm{p}^{6} 3 \mathrm{~d}^{19} 4 \mathrm{~s}^{2} 4 \mathrm{p}^{6}\) (2) \(1 \mathrm{~s}^{2} 2 \mathrm{~s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{~s}^{2} 3 \mathrm{p}^{6} 3 \mathrm{~d}^{5} 4 \mathrm{~s}^{2}\) (3) \(1 \mathrm{~s}^{2} 2 \mathrm{~s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{~s}^{2} 3 \mathrm{p}^{6} 3 \mathrm{~d}^{6} 4 \mathrm{~s}^{1}\) (4) \(1 \mathrm{~s}^{2} 2 \mathrm{~s}^{2} 2 \mathrm{p}^{6} 3 \mathrm{~s}^{2} 3 \mathrm{p}^{6} 3 \mathrm{~d}^{10} 4 \mathrm{~s}^{2} 4 \mathrm{p}^{5}\)

Short answer

Option 2

Step-by-step solution

- Identify the element with atomic number 43

The element with atomic number 43 is Technetium (Tc).

- Determine the group of Technetium

Technetium belongs to Group 7 of the periodic table.

- Find the element just above Technetium in Group 7

The element directly above Technetium (Tc) in Group 7 is Manganese (Mn), with atomic number 25.

- Write the electronic configuration for Manganese

The electronic configuration for Manganese (Mn) with atomic number 25 is: \[1\text{ s}^{2} 2\text{ s}^{2} 2\text{ p}^{6} 3\text{ s}^{2} 3\text{ p}^{6} 3\text{d}^{5} 4\text{ s}^{2}\]

- Match the configuration with the given options

Option (2) matches the electronic configuration of Manganese: \[1\text{ s}^{2} 2\text{ s}^{2} 2\text{ p}^{6} 3\text{ s}^{2} 3\text{ p}^{6} 3\text{d}^{5} 4\text{ s}^{2}\]

Key concepts

Electronic Configuration

Every atom has a unique way electrons fill up its energy levels, described by its electronic configuration. The structure of an atom consists of energy levels known as shells (designated by the principal quantum number, n) and subshells (s, p, d, f).
Electrons fill the lowest energy levels first, following the Aufbau principle. This filling includes specific orders of subshells, as described by Hund's rule and the Pauli exclusion principle.
Understanding the electronic configuration helps identify an element's position in the periodic table and predict its chemical behavior.
For example, manganese (Mn) with atomic number 25, has the electronic configuration: \(1\text{ s}^{2} 2\text{ s}^{2} 2\text{ p}^{6} 3\text{ s}^{2} 3\text{ p}^{6} 3\text{d}^{5} 4\text{ s}^{2}\). This means manganese has:

• 2 electrons in the first shell (1s)
• 8 electrons in the second shell (2s and 2p)
• 13 electrons in the third shell (3s, 3p, 3d)
• 2 electrons in the fourth shell (4s)

Hence, its electronic configuration determines its chemical properties and reactivity.

Atomic Number

The atomic number of an element is the number of protons found in the nucleus of an atom. This number is unique to each element and serves as an identifying feature.
The atomic number determines the position of an element in the periodic table and defines its elemental identity.
For example, Technetium (Tc) has an atomic number of 43, meaning its nucleus contains 43 protons. Being positioned in Group 7, its properties can be compared to other elements in the same group. Manganese (Mn), with an atomic number of 25, lies directly above Technetium in Group 7.
This property also helps in understanding electronic configuration since knowing the number of protons helps predict the amount of electrons in a neutral atom. A correct understanding of atomic numbers is crucial for mastering concepts related to the periodic table and chemical bonding.

Element Groups

Elements in the periodic table are organized into groups and periods, with each group consisting of elements that exhibit similar chemical properties. Group elements have the same number of valence electrons, which is integral to their chemical reactions.
Taking Group 7 as an example: elements such as Manganese (Mn), Technetium (Tc), and others exhibit similarities due to their identical valence electron count.

• Manganese (Mn) has the electronic configuration: \(1\text{ s}^{2} 2\text{ s}^{2} 2\text{ p}^{6} 3\text{ s}^{2} 3\text{ p}^{6} 3\text{d}^{5} 4\text{ s}^{2}\).
• Technetium (Tc) shares this group, with slightly different properties due to its higher atomic number (43).

Each transition from one element to another within the group introduces slight nuances in properties but maintains the core characteristics defined by valence electron configurations. Therefore, by understanding the group and period position of an element, one can predict its reactivity, bonding patterns, and other chemical behaviors.