Question

IUPAC name of the compound for BrC1CCC(C2CCC(Br)CC2)CC1 is (1) \(4,4^{\prime}-\) dibromo \(-1,1^{\prime}\) -dicyclohexyl (2) \(4,4^{\prime}-\) dibromo \(-1,1^{\prime}\) -bicyclohexane (3) I-bromo-4-(4'-bromo) bicyclohexane (4) None of these

Short answer

4,4'-dibromo-1,1'-bicyclohexane.

Step-by-step solution

Identify the Base Structure

Analyze the given compound structure to identify the primary carbon chain or rings. In this case, the structure consists of two cyclohexane rings joined together.

Determine the Substituents

Notice the two bromine (Br) atoms attached to carbon atoms in separate cyclohexane rings. Identify their positions on the rings.

Number the Carbon Atoms

Number the carbon atoms in each cyclohexane ring such that the substituents (Br atoms) get the lowest possible numbers. Here, both bromine atoms take the 4th position in their respective rings.

Name the Compound

Formulate the IUPAC name by specifying the positions of the substituents and the base structure. The correct name is: 4,4'-dibromo-1,1'-bicyclohexane.

Key concepts

organic chemistry

Organic chemistry is the branch of chemistry that deals with the structure, properties, composition, reactions, and synthesis of carbon-containing compounds. These compounds can range from simple molecules like methane to complex structures like proteins and DNA.
Carbon atoms form the backbone of organic molecules since they can create strong covalent bonds with other atoms, including other carbon atoms. This versatility allows for a vast diversity of organic compounds.
Understanding organic chemistry involves learning about various functional groups, chemical reactions, and molecular structures. Functional groups such as hydroxyl (-OH), carbonyl (C=O), and halides (like bromine) significantly impact the chemical behavior of compounds. Mastery of organic chemistry provides a foundation for advanced fields like biochemistry, pharmacology, and materials science.

cyclohexane structure

Cyclohexane is a cycloalkane with the molecular formula C6H12, consisting of a ring-shaped structure composed of six carbon atoms each bonded to two hydrogen atoms.
The structure of cyclohexane is unique because it does not remain flat but adopts different conformations to minimize strain and increase stability. The most common and stable conformations are the 'chair' and 'boat' forms.
In the chair conformation, the carbon atoms are arranged in a way that reduces torsional strain and steric hindrance, making it the most energetically favorable. The boat conformation, although less stable, also plays a role in the dynamic behavior of cyclohexane rings.
Understanding cyclohexane's structure is essential for determining the correct numbering of carbon atoms and substituent positioning in more complex molecules.

substituent positions

In organic chemistry, substituents are atoms or groups of atoms that replace hydrogen atoms on a parent hydrocarbon chain or ring. Their positions on the main structure greatly influence the compound's properties and its IUPAC name.
Numbering the carbon atoms correctly is crucial for accurately describing the substituent positions. The numbering should start from the carbon that gives the lowest possible numbers to the substituents.
For instance, in a cyclohexane ring with two bromine substituents, the positions must be identified and numbered to ensure clarity in the IUPAC name. In our example, each bromine is located on the 4th carbon atom of their respective cyclohexane rings, resulting in the name 4,4′-dibromo-1,1′-bicyclohexane.
This proper identification and naming help in clearly communicating the molecular structure and ensuring consistency across chemical literature and databases.