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Which is not correct? (1) Ge(OH)2 is amphoteric. (2) GeCl2 is more stable than GeCl4. (3) GeO2 is less acidic than SiO2. (4) GeCl4 in HCl forms [GeCl6]2.

Short Answer

Expert verified
Option 2 is incorrect.

Step by step solution

01

Analyze Option 1

Check if Ge(OH)2 is amphoteric. An amphoteric substance can act both as an acid and as a base. Since Ge(OH)2 can exhibit this behavior, it can be classified as amphoteric. Therefore, this option is correct.
02

Analyze Option 2

Verify the stability of GeCl2 compared to GeCl4. Generally, GeCl4 is more stable due to its complete octet configuration around germanium. Hence, this option is incorrect.
03

Analyze Option 3

Evaluate the acidity of GeO2 compared to SiO2. GeO2 is indeed less acidic than SiO2, confirming this option as correct.
04

Analyze Option 4

Check the formation of [GeCl6]2 in presence of HCl. GeCl4 does form the anionic complex [GeCl6]2, making this option correct.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Amphoteric substances
Understanding amphoteric substances is key in inorganic chemistry. Amphoteric substances can act both as acids and bases. This dual behavior allows them to neutralize both acids and bases, making them unique.
For example, Ge(OH)2 is amphoteric, meaning it can donate protons (acting as an acid) or accept protons (acting as a base) depending on the reacting substance.
Another common amphoteric substance is aluminum hydroxide Al(OH)3.
Recognizing amphoteric substances helps in predicting reactions and understanding compound behavior in different environments.
Stability of compounds
The stability of compounds is vital in determining how they react and persist under different conditions. For instance, GeCl4 is more stable than GeCl2.
This is because GeCl4 achieves a full octet, satisfying the octet rule, which makes it less reactive and more stable.
On the other hand, GeCl2 does not have a complete octet, making it more reactive and less stable. This stability impacts how these compounds are used and handled in practical applications.
Acidity comparison
Comparing the acidity of compounds like GeO2 and SiO2 can be quite insightful.
Acidity is the ability of a substance to donate protons. SiO2 (Silicon dioxide) is more acidic than GeO2 (Germanium dioxide).
This happens because Silicon (Si) is smaller and more electronegative than Germanium (Ge), leading to a stronger attraction of electrons towards the oxygen in SiO2.
This makes SiO2 more likely to donate protons compared to GeO2. Understanding these acidity trends aids in predicting reactions and compatibility between compounds.
Anionic complexes
Anionic complexes are negatively charged groups consisting of a central metal atom bonded to surrounding ligands.
For example, GeCl4 in HCl forms the anionic complex [GeCl6]2.
This occurs because GeCl4 reacts with additional chlorine ions (\text{Cl}^{-}) from hydrochloric acid (HCl), resulting in [GeCl6]2.
Anionic complexes are crucial in various chemical processes and applications, including catalysis and the formation of more complex structures.

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