Chapter 9: Problem 116
Using grammatically correct sentences, describe the periodic trends for atomic size, ionization energy, and metallic character.
Short Answer
Expert verified
Atomic size decreases across a period and increases down a group. Ionization energy increases across a period and decreases down a group. Metallic character decreases across a period and increases down a group.
Step by step solution
01
Explain Atomic Size Trend
Atomic size, or atomic radius, generally decreases from left to right across a period in the periodic table. This is because as you move across a period, protons are added to the nucleus, increasing the nuclear charge. This results in a greater force of attraction exerted on the electrons by the nucleus, leading to a smaller atomic radius. Conversely, atomic size generally increases down a group as the number of electron shells increases, which results in a larger radius due to the greater distance between the outer electrons and the nucleus.
02
Describe Ionization Energy Trend
Ionization energy is the energy required to remove an electron from an atom in the gaseous state. Ionization energy generally increases across a period from left to right due to the increasing nuclear charge, which makes it more difficult to remove an electron as atoms hold onto their electrons more tightly. Down a group, ionization energy generally decreases because the outer electrons are farther from the nucleus and are more easily removed due to the lesser effective nuclear charge experienced by these electrons.
03
Outline Metallic Character Trend
Metallic character refers to the level at which an element exhibits properties of metals, such as malleability, ductility, and good electrical conductivity. Metallic character generally decreases across a period from left to right. This is because elements become less metallic as they gain more electrons and increase their ability to attract electrons (non-metallic behavior). Down a group, metallic character increases, because atoms have more electron shells and the outermost electrons are less tightly bound to the nucleus, making these elements more likely to lose electrons and exhibit metallic properties.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Atomic Size
Understanding atomic size is fundamental in comprehending the organizing principles of the periodic table. Atomic size, referred to as atomic radius, offers insights into the behavior of elements in various chemical reactions. Beginning to the left of the periodic table, as we proceed right across a period, the atomic size decreases. This trend can be attributed to the increase in the number of protons within the nucleus, leading to a stronger pull on the electrons closer to the center, hence a decreased radius.
Conversely, as we descend down any group, the atomic size increases, due to the addition of electron shells, or layers. These additional shells increase the physical distance between the outermost electrons and the nucleus, causing a notably larger atomic radius. The significance of this concept lies in its impact on the element's chemical properties, such as bonding behaviors and reactivity.
Conversely, as we descend down any group, the atomic size increases, due to the addition of electron shells, or layers. These additional shells increase the physical distance between the outermost electrons and the nucleus, causing a notably larger atomic radius. The significance of this concept lies in its impact on the element's chemical properties, such as bonding behaviors and reactivity.
Ionization Energy
The term ionization energy may sound complex, but it plays a crucial role in understanding chemical reactions. Ionization energy refers to the amount of energy required to remove an electron from the outer shell of an atom in its gaseous state. Across the periodic table, from left to right, there is an observable increase in ionization energy. This is because as the atoms gain more protons in their nucleus, they exert a stronger attraction force on the electrons, making it more challenging to remove these negatively charged particles.
As we look down groups, the opposite trend emerges – ionization energy decreases. The outermost electrons, being further away from the nuclear charge, experience a lesser hold and can be removed with less energy. This concept is vital in predicting the reactivity of an element and how it will interact with other substances.
As we look down groups, the opposite trend emerges – ionization energy decreases. The outermost electrons, being further away from the nuclear charge, experience a lesser hold and can be removed with less energy. This concept is vital in predicting the reactivity of an element and how it will interact with other substances.
Metallic Character
Delving into the metallic character of elements reveals their fascinating transition from metal to nonmetal across the periodic table. To the left of the periodic table, we encounter elements with strong metallic characteristics. These elements tend to be malleable, ductile, and excellent conductors of electricity. As we move across a period from left to right, the metallic character diminishes. The elements transition towards more non-metallic behavior; they gain electrons more readily and hold them more tightly, moving away from typical metallic properties.
In contrast, moving down a group showcases an increase in metallic behaviors. The growing number of electron shells allows the outer electrons to be less tightly bound to the atom's nucleus, promoting the loss of electrons which is a quintessential trait of metals. Understanding this trend is crucial when exploring the various applications of elements, from constructing materials to their roles in electrical circuits.
In contrast, moving down a group showcases an increase in metallic behaviors. The growing number of electron shells allows the outer electrons to be less tightly bound to the atom's nucleus, promoting the loss of electrons which is a quintessential trait of metals. Understanding this trend is crucial when exploring the various applications of elements, from constructing materials to their roles in electrical circuits.