Chapter 16: Problem 94
How does the collision model account for the fact that a reaction proceeds faster when the concentrations of the reactants are increased?
Chapter 16: Problem 94
How does the collision model account for the fact that a reaction proceeds faster when the concentrations of the reactants are increased?
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Get started for freeFor the reaction $$\mathrm{CaCO}_{3}(s) \rightleftharpoons \mathrm{CaO}(s)+\mathrm{CO}_{2}(g)$$ it is found that at equilibrium \(\left[\mathrm{CO}_{2}\right]=2.1 \times 10^{-3} \mathrm{M}\) at a particular temperature. Calculate \(K\) for the reaction at this temperature.
For the reaction system $$4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \rightleftharpoons 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g)$$ which has already reached a state of equilibrium, predict the effect that each of the following changes will have on the position of the equilibrium. Tell whether the equilibrium will shift to the right, will shift to the left, or will not be affected. a. The pressure of oxygen is increased by injecting one additional mole of oxygen into the reaction vessel. b. A desiccant (a material that absorbs water) is added to the system. c. The system is compressed and the ammonia liquefies.
Why does the amount of excess solid solute present in a solution not affect the amount of solute that ultimately dissolves in a given amount of solvent?
For the process $$\mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g) \rightleftharpoons \mathrm{CO}_{2}(g)+\mathrm{H}_{2}(g)$$ it is found that the equilibrium concentrations at a particular temperature are \(\left[\mathrm{H}_{2}\right]=1.4 \mathrm{M},\left[\mathrm{CO}_{2}\right]=1.3\) \(M,[\mathrm{CO}]=0.71 \mathrm{M},\) and \(\left[\mathrm{H}_{2} \mathrm{O}\right]=0.66 \mathrm{M} .\) Calculate the equilibrium constant \(K\) for the reaction under these conditions.
For the reaction $$\mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g)$$ the equilibrium constant \(K\) has the value \(8.1 \times 10^{-3}\) at a particular temperature. If the concentration of \(\mathrm{NO}_{2}(g)\) is found to be \(0.0021 \mathrm{M}\) in the equilibrium system, what is the concentration of \(\mathrm{N}_{2} \mathrm{O}_{4}(g)\) under these conditions?
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