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What does Boyle's law tell us about the effect of pressure on the volume of a gas?

Short Answer

Expert verified
Boyle's Law tells us that pressure and volume are inversely proportional for a given gas at constant temperature. If pressure increases, volume decreases, and vice versa.

Step by step solution

01

Understand Boyle's Law

Boyle's Law, named after Robert Boyle, states that at a fixed temperature, the pressure \(P\) and volume \(V\) of a given amount of gas are inversely proportional. This can be mathematically expressed as \(PV = k\), where \(k\) is a constant. The law implies that when the pressure of a gas increases, the volume decreases and vice versa, assuming the temperature remains constant.
02

Explain the effect of pressure on the volume of a gas

According to Boyle's Law, when the pressure applied to a gas is increased, the volume of the gas decreases, provided the temperature remains constant. Similarly, if the pressure applied to a gas is decreased, the volume of the gas increases. This inverse relationship between pressure and volume highlights the elastic nature of gases.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Gas Pressure-Volume Relationship
When studying the behavior of gases, understanding the gas pressure-volume relationship is fundamental. Boyle's Law is a principle that captures this relationship elegantly. It posits that, for a fixed quantity of gas at constant temperature, the pressure of the gas is inversely related to its volume. This means that if you increase the pressure exerted on the gas, its volume will decrease; if you decrease the pressure, the volume will increase.

To visualize this, imagine a syringe filled with gas: if you push the plunger in, thereby decreasing the volume within the syringe, you’ll notice the pressure increases, as it gets harder to push. This concept also applies to numerous everyday phenomena, such as the compression of air within a bicycle pump or the expansion of the lungs when inhaling. The formula reflecting Boyle's Law can be represented as \( PV = k \), where \( P \) is pressure, \( V \) is volume, and \( k \) is a constant for a given amount of gas at a specific temperature. This equation is the mathematical embodiment of the relationship between gas pressure and volume and is crucial for predicting how a gas will behave under different pressures.
Inversely Proportional Gas Behavior
Inversely proportional relationships, like the one described by Boyle's Law, are an essential concept in the study of gases. To be inversely proportional means that as one variable increases, the other decreases in such a way that the product of the two remains constant. In the context of gas laws, this behavior explains how gases compress and expand in response to changes in pressure.

To comprehend this concept better, consider a balloon. When you compress it, you reduce its volume, and the trapped air molecules inside are forced closer together, increasing pressure. Conversely, when the balloon is allowed to expand, the volume increases, and the pressure inside the balloon decreases as the molecules are less crowded. Boyle's law is the reason why divers need to be cautious of the volume of air in their equipment as they ascend or descend, where pressure changes significantly. The inversely proportional gas behavior is not only important in academic contexts but also in real-world applications like respiratory systems, automotive engines, and even meteorology.
Robert Boyle and His Contribution to Science
Robert Boyle, a pioneering figure of the scientific revolution and one of the founders of modern chemistry, made significant contributions to science, including the formulation of Boyle's Law. Born in the 17th century, his work marked the beginning of experimental scientific methodology in chemistry. Boyle was fascinated by the properties of gases and was among the first to define an element in chemical terms.

His most notable contribution, Boyle's Law, not only describes the inversely proportional relationship between the pressure and volume of a gas but also set the stage for further research into the behavior of gases, and the field now known as physical chemistry. Robert Boyle's diligent approach to experimentation and his application of mathematical relationships to chemistry laid the groundwork for scientists such as Charles-Augustin de Coulomb and Jacques Charles, who furthered the study of gases and their properties. Boyle's work remains fundamental in various scientific fields, impacting both theoretical perspectives and technological advancements.

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Most popular questions from this chapter

Given the following amounts of gases, calculate the number of moles of each gas. Calculate the volume each amount of gas would occupy at STP. (a) \(5.8 \mathrm{~g} \mathrm{NH}_{3}\) (b) \(48 \mathrm{~g} \mathrm{O}_{2}\) (c) \(10.8 \mathrm{~g}\) He

Given the following volumes of gases at STP, calculate the number of moles of each gas and the mass of the gas. (a) \(135 \mathrm{~mL} \mathrm{H}_{2}\) (b) \(8.96 \mathrm{LN}_{2}\) (c) \(0.75 \mathrm{~L} \mathrm{He}\)

For a gas under a given initial set of conditions, calculate the final value for the variable indicated if the other two variables change as described in the following table. $$ \begin{array}{|l|c|c|c|} \hline \text { Initial volume } & 2.50 \mathrm{~L} & 125 \mathrm{~L} & 455 \mathrm{~mL} \\ \hline \text { Initial pressure } & 0.50 \mathrm{~atm} & 0.250 \mathrm{~atm} & 200.0 \text { torr } \\ \hline \text { Initial temperature } & 20.0^{\circ} \mathrm{C} & 25^{\circ} \mathrm{C} & 300 \mathrm{~K} \\ \hline \text { Final volume } & ? & 62.0 \mathrm{~L} & 200.0 \mathrm{~mL} \\ \hline \text { Final pressure } & 760.0 \text { torr } & 100.0 \text { torr } & ? \\ \hline \text { Final temperature } & 0.0^{\circ} \mathrm{C} & ? & 327^{\circ} \mathrm{C} \\ \hline \end{array} $$

Assume that the volume of a fixed amount of gas in a rigid container does not change. Calculate the pressure the gas would exert if the temperature were changed as shown in the following table. $$ \begin{array}{|c|c|c|c|} \hline \begin{array}{c} \text { Initial } \\ \text { Pressure } \end{array} & \begin{array}{c} \text { Initial } \\ \text { Temperature } \end{array} & \begin{array}{c} \text { Final } \\ \text { Temperature } \end{array} & \begin{array}{c} \text { Final } \\ \text { Pressure } \end{array} \\ \hline 255 \text { torr } & 225 \mathrm{~K} & 315 \mathrm{~K} & ? \\ \hline 895 \text { torr } & 25^{\circ} \mathrm{C} & 206 \mathrm{~K} & ? \\ \hline 2.74 \mathrm{~atm} & 150^{\circ} \mathrm{C} & 23^{\circ} \mathrm{C} & ? \\\ \hline \end{array} $$

At constant temperature, the pressure of a gas is inversely proportional to its volume. Explain this relationship in molecular terms.

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