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(a) Write an equation to show how Mg reacts with \(\mathrm{N}_{2}\) when heated. (b) Suggest how the product reacts with water.

Short Answer

Expert verified
(a) \( 3\mathrm{Mg} + \mathrm{N}_2 \rightarrow \mathrm{Mg}_3 \mathrm{N}_2 \). (b) \( \mathrm{Mg}_3 \mathrm{N}_2 + 6\mathrm{H}_2\mathrm{O} \rightarrow 3\mathrm{Mg(OH)}_2 + 2\mathrm{NH}_3 \).

Step by step solution

01

Understanding the Reactants

First, identify the reactants in the reaction. The reactants in this equation are magnesium (Mg) and nitrogen gas \( \mathrm{N}_2 \). When heated, magnesium reacts with nitrogen.
02

Balanced Equation for Mg and N2

Write the chemical equation showing the reaction of Mg with \( \mathrm{N}_2 \) to form magnesium nitride \( \mathrm{Mg}_3 \mathrm{N}_2 \). The balanced chemical equation is: \[3\mathrm{Mg} + \mathrm{N}_2 \rightarrow \mathrm{Mg}_3 \mathrm{N}_2\]
03

Identifying Product Reaction with Water

The product, magnesium nitride \( \mathrm{Mg}_3 \mathrm{N}_2 \), will react with water \( \mathrm{H}_2\mathrm{O} \) in the following way: \( \mathrm{Mg}_3 \mathrm{N}_2 \) reacts with water to produce magnesium hydroxide \( \mathrm{Mg(OH)}_2 \) and ammonia \( \mathrm{NH}_3 \).
04

Balanced Equation for Reaction with Water

Write and balance the chemical equation for the reaction of \( \mathrm{Mg}_3 \mathrm{N}_2 \) with \( \mathrm{H}_2\mathrm{O} \). The balanced equation is: \[\mathrm{Mg}_3 \mathrm{N}_2 + 6\mathrm{H}_2\mathrm{O} \rightarrow 3\mathrm{Mg(OH)}_2 + 2\mathrm{NH}_3\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Magnesium Nitride
Magnesium nitride is an intriguing compound that forms when magnesium (Mg) reacts with nitrogen gas (\( \mathrm{N}_2 \)). This reaction typically occurs when the two elements are heated together. Magnesium, a metal in group 2 of the periodic table, is quite reactive, especially at elevated temperatures. When it combines with nitrogen, a gaseous non-metal, they form magnesium nitride, symbolized as \( \mathrm{Mg}_3 \mathrm{N}_2 \).

The reaction to form magnesium nitride is a type of synthesis reaction, where multiple reactants combine to form a single product. The chemical equation for this reaction is:\[3\mathrm{Mg} + \mathrm{N}_2 \rightarrow \mathrm{Mg}_3 \mathrm{N}_2\]
  • The equation shows that three magnesium atoms react with one nitrogen molecule.
  • This must be balanced with respect to both reactants and the product.
  • It indicates a stoichiometric relationship where magnesium and nitrogen combine in a 3:1 ratio to form magnesium nitride.
Understanding magnesium nitride's formation and properties is crucial because its reactivity plays a role in various chemical processes and potential industrial applications.
Crafting Chemical Equations
Chemical equations are a way of representing chemical reactions using symbols for the elements and compounds involved. Crafting a chemical equation requires a clear understanding of the reactants and products involved in the reaction. Let's break it down with the example given:

When magnesium reacts with nitrogen, the equation is:\[3\mathrm{Mg} + \mathrm{N}_2 \rightarrow \mathrm{Mg}_3 \mathrm{N}_2\]This equation represents the synthesis of magnesium nitride. Here's how to approach such equations:
  • Start by writing down the symbols for each reactant and product.
  • Ensure the equation is balanced—meaning the same number of each type of atom appears on both sides of the arrow.
  • Balance the equation by adjusting coefficients, which are the numbers placed in front of the chemical formulas.
Balancing chemical equations ensures that the law of conservation of mass is followed, which states that matter cannot be created or destroyed. For magnesium nitride, this balancing is crucial for predicting how much of each substance is involved in or produced by the reaction.
Exploring the Reaction with Water
Magnesium nitride, once formed, has the interesting property of reacting with water. This is a decomposition reaction where magnesium nitride reacts with water to form new products. The balanced chemical equation for this interaction is:\[\mathrm{Mg}_3 \mathrm{N}_2 + 6\mathrm{H}_2\mathrm{O} \rightarrow 3\mathrm{Mg(OH)}_2 + 2\mathrm{NH}_3\]Here’s what happens in this reaction:
  • Magnesium nitride breaks down when it reacts with water.
  • It forms magnesium hydroxide \( \mathrm{Mg(OH)}_2 \), a white, solid compound.
  • Ammonia \( \mathrm{NH}_3 \), a gas with a sharp smell, is also produced.
This reaction demonstrates the reactivity of magnesium nitride. Understanding reactions like this is important for learning how different chemicals interact, which can be applied in fields ranging from industrial processes to environmental science. The conversion of solid magnesium nitride into hydroxy compound and ammonia gas is a practical example of how chemistry can transform substances.

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Most popular questions from this chapter

Comment on the following statements. (a) \(\mathrm{Na}_{2} \mathrm{S}\) adopts a solid state structure that is related to that of CaF \(_{2}\) (b) \(\left[\mathrm{C}_{3}\right]^{4}, \mathrm{CO}_{2}\) and \(\left[\mathrm{CN}_{2}\right]^{2-}\) are isoelectronic species. (c) \(\operatorname{Be}(\mathrm{OH})_{2}\) is virtually insoluble in water, but is soluble in aqueous solutions containing excess hydroxide ions. (d) \(\mathrm{MgO}\) is used as a refractory material.

(a) \(A\) 6-coordinate complex may be obtained by crystallizing anhydrous CaI \(_{2}\) from THF solution at \(253 \mathrm{K}\). In contrast, when anhydrous \(\mathrm{Bal}_{2}\) is crystallized from THF at \(253 \mathrm{K},\) a 7 -coordinate complex is isolated. Suggest structures for the two complexes, and comment on possible isomerism and factors that may favour one particular isomer in each case. Rationalize why \(\mathrm{CaI}_{2}\) and \(\mathrm{BaI}_{2}\) form complexes with THF that have different coordination numbers. (b) Which of the following compounds are sparingly soluble in water, which are soluble without reaction, and which react with water: \(\mathrm{BaSO}_{4}, \mathrm{CaO}, \mathrm{MgCO}_{3}\) \(\mathrm{Mg}(\mathrm{OH})_{2}, \mathrm{SrH}_{2}, \mathrm{BeCl}_{2}, \mathrm{Mg}\left(\mathrm{ClO}_{4}\right)_{2}, \mathrm{CaF}_{2}, \mathrm{BaCl}_{2}\) \(\mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2} ?\) For the compounds that react with water, what are the products formed?

Write balanced equations for the following reactions: (a) the thermal decomposition of \(\left[\mathrm{NH}_{4}\right]_{2}\left[\mathrm{BeF}_{4}\right]\) (b) the reaction between \(\mathrm{NaCl}\) and \(\mathrm{BeCl}_{2}\) (c) the dissolution of BeF \(_{2}\) in water.

Write a short account that justifies the so-called diagonal relationship between Li and Mg.

(a) \(\mathrm{A}\) group 2 metal, \(\mathrm{M}\), dissolves in liquid \(\mathrm{NH}_{3}\), and from the solution, compound \(\mathbf{A}\) can be isolated. A slowly decomposes to B with liberation of \(\mathrm{NH}_{3}\) and a gas \(\mathrm{C}\) Metal \(\mathbf{M}\) gives a crimson flame test; through blue glass, the flame appears pale purple. Suggest identities for \(\mathbf{M}, \mathbf{A}, \mathbf{B}\) and \(\mathbf{C}\) (b) The group 2 metal \(\mathbf{X}\) occurs naturally in great abundance as the carbonate. Metal X reacts with cold water, forming compound \(\mathbf{D}\), which is a strong base. Aqueous solutions of \(\mathbf{D}\) are used in qualitative tests for \(\mathrm{CO}_{2} .\) X combines with \(\mathrm{H}_{2}\) to give a saline hydride that is used as a drying agent. Identify \(\mathbf{X}\) and \(\mathbf{D}\). Write equations for the reaction of \(\mathbf{X}\) with \(\mathrm{H}_{2} \mathrm{O}\) and of the hydride of \(\mathbf{X}\) with \(\mathrm{H}_{2} \mathrm{O}\). Explain how you would carry out a qualitative test for \(\mathrm{CO}_{2}\) using an aqueous solution of \(\mathbf{D}\)

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