Question

Account for the statement: Zinc, cadmium and mercury are not strictly transition elements.

Short answer

Zinc, cadmium, and mercury typically have completely filled d-orbitals, differing from the conventional definition of transition elements which states that they should have partially filled d-orbitals. Because of this, they do not exhibit multiple oxidation states, a feature common to transition metals. Therefore, they are not considered as strict transition elements.

Step-by-step solution

Definition of Transition Elements

Transition elements are defined as elements that have partially filled d orbitals. They typically exhibit multiple oxidation states and are often characterized by their capacity for forming complex ions with ligands.

Zinc, Cadmium, and Mercury Electronic Configurations

Looking at the electronic configurations of Zinc (Zn - [Ar] 3d10 4s2), Cadmium (Cd - [Kr] 4d10 5s2), and Mercury (Hg - [Xe] 4f14 5d10 6s2), it is observed that all of them have completely filled d-orbitals. This is contrary to the general definition of transition elements.

Inference

Due to their complete d-orbitals, zinc, cadmium, and mercury do not show variety in the oxidation states, a crucial attribute of transition elements. Thus, they are not often considered as strict transition metals, even though they are part of the d-block.

Key concepts

d-block elements

To understand transition elements, it's important to start with the d-block of the periodic table. The periodic table is divided into several blocks based on electron configurations, primarily the s, p, d, and f blocks. The d-block elements are those where the last electron enters the d orbital. These elements are found in the center of the periodic table, encompassing groups 3 through 12.

These elements are versatile and play crucial roles in chemistry due to their unique properties, such as the ability to exist in several oxidation states and the formation of colored compounds. Although not every d-block element acts as a transition metal, almost all transition metals belong to the d-block.

The reason zinc, cadmium, and mercury are part of the d-block but not counted as true transition metals is because their d subshells are fully filled. In general, a transition metal must have an incomplete d subshell in its elemental or common oxidation states.

oxidation states

Oxidation states are the charges an atom can attain through gaining or losing electrons. Transition elements are renowned for their multiple oxidation states. This characteristic is due to the relatively small energy differences between the s and d orbitals, allowing for varied options of electron distribution.

In chemical reactions, the transition metals adjust their oxidation states by losing different numbers of d and s electrons. This property leads to vast diversity in their chemical behavior and utility. For instance, iron can exist in oxidation states of +2 and +3, while manganese has states ranging from +2 to +7.

Zinc, cadmium, and mercury primarily exhibit a +2 oxidation state. Since their d orbitals are filled, they lack the flexibility of providing electrons for multiple oxidation states, which further explains why these elements are not considered transition metals by some definitions.

electronic configuration

Electronic configuration is a detailed description of the arrangement of electrons around an atom's nucleus. It helps explain the chemistry and properties of different elements.

In transition metals, this configuration frequently includes partially filled d orbitals. This feature allows these elements to form colored compounds, partake in variable oxidation states, and engage in extensive catalysis.

When we look at zinc, cadmium, and mercury, their electronic configurations reveal filled d orbitals:

• Zinc: [Ar] 3d¹⁰ 4s²
• Cadmium: [Kr] 4d¹⁰ 5s²
• Mercury: [Xe] 4f¹⁴ 5d¹⁰ 6s²

Because their d orbitals are full, they do not meet the strict criterion for transition metal classification, which requires partially filled d orbitals. This affects their chemical behavior and distinguishes them from their traditional transition metal peers.

complex ion formation

Complex ion formation is a hallmark of transition metals due to their ability to bind with various ligands. Ligands are ions or molecules that donate electron pairs to form coordinate bonds with the central metal atom or ion. This results in complex structures with distinctive properties, such as color and magnetism.

Transition metals with partially filled d orbitals can readily form these complex ions. For example, in the case of iron, it forms complex ions with many ligands, significantly altering its chemical reactions and stability.

Zinc, cadmium, and mercury, on the other hand, do not as extensively form complex ions. While they can engage in such formations, the complete filling of their d orbitals and their limited oxidation states reduce their potential for complex ion formation. This limitation is another reason why these elements are not categorized as true transition metals.