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For each reaction listed, identify the proton donor or acid and the proton acceptor or base. Label each conjugate acid-base pair. a. \(\mathrm{CH}_{3} \mathrm{COOH}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftarrows\) \(\mathrm{H}_{3} \mathrm{O}+(a q)+\mathrm{CH}_{3} \mathrm{COO}-(a q)\) b. \(\mathrm{HCO}_{3}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftarrows\) \(\mathrm{H}_{2} \mathrm{CO}_{3}(a q)+\mathrm{OH}^{-}(a q)\) c. \(\mathrm{HNO}_{3}+\mathrm{SO}_{4}^{2-} \longrightarrow \mathrm{HSO}_{4}^{-}+\mathrm{NO}_{3}^{-}\)

Short Answer

Expert verified
a. Acid: \(\text{CH}_3\text{COOH}\), Base: \(\text{H}_2\text{O}\); Conjugates: \(\text{H}_3\text{O}^+\text{ (aq)}\), \(\text{CH}_3\text{COO}^-\text{ (aq)}\). b. Acid: \(\text{HCO}_3^{-}\text{ (aq)}\), Base: \(\text{H}_2\text{O}\); Conjugates: \(\text{OH}^-\text{ (aq)}\), \(\text{H}_2\text{CO}_3\text{ (aq)}\). c. Acid: \(\text{HNO}_3\), Base: \(\text{SO}_4^{2-}\); Conjugates: \(\text{HSO}_4^{-}\), \(\text{NO}_3^{-}\).

Step by step solution

01

- Identify the Reactants and Products (Reaction a)

For the reaction \(\text{CH}_3\text{COOH (aq)} + \text{H}_2\text{O (l)} \rightleftarrows \text{H}_3\text{O}^{+} \text{(aq)} + \text{CH}_3\text{COO}^{-}\text{ (aq)}\)}, identify the reactants (\( \text{CH}_3\text{COOH} \) and \(\text{H}_2\text{O} \)), and the products \(\text{H}_3\text{O}^{+} \) and \(\text{CH}_3\text{COO}^{-}\text{ (aq)}\)).
02

- Identify the Acid and Base (Reaction a)

Determine which species donates a proton (\( \text{H}^+ \)). \(\text{CH}_3\text{COOH} \) donates a proton to \(\text{H}_2\text{O} \) forming \(\text{H}_3\text{O}^+ \), making \(\text{CH}_3\text{COOH} \) the acid and \(\text{H}_2\text{O} \) the base.
03

- Identify the Conjugate Pairs (Reaction a)

Identify the conjugate acid-base pairs: \(\text{CH}_3\text{COOH} \) (acid) and \(\text{CH}_3\text{COO}^-\text{ (aq)} \) (conjugate base), and \(\text{H}_2\text{O} \) (base) and \(\text{H}_3\text{O}^+\text{ (aq)} \) (conjugate acid).
04

- Identify the Reactants and Products (Reaction b)

For the reaction \(\text{HCO}_3^{-}\text{ (aq)} + \text{H}_2\text{O (l)} \rightleftarrows \text{H}_2\text{CO}_3\text{ (aq)} + \text{OH}^-\text{ (aq)}\), identify the reactants (\( \text{HCO}_3^{-} \) and \(\text{H}_2\text{O} \)), and the products \(\text{H}_2\text{CO}_3 \) and \(\text{OH}^-\)).
05

- Identify the Acid and Base (Reaction b)

Determine which species donates a proton (\( \text{H}^+ \)). \(\text{HCO}_3^{-} \) donates a proton to \(\text{H}_2\text{O} \) forming \(\text{H}_2\text{CO}_3 \), making \(\text{HCO}_3^{-} \) the acid and \(\text{H}_2\text{O} \) the base.
06

- Identify the Conjugate Pairs (Reaction b)

Identify the conjugate acid-base pairs: \(\text{HCO}_3^{-}\text{ (aq)} \) (acid) and \(\text{CO}_3^{2-}\text{ (aq)} \) (conjugate base), and \(\text{H}_2\text{O} \) (base) and \(\text{OH}^- \) (conjugate acid).
07

- Identify the Reactants and Products (Reaction c)

For the reaction \(\text{HNO}_3 + \text{SO}_4^{2-} \rightarrow \text{HSO}_4^{-} + \text{NO}_3^{-} \), identify the reactants (\( \text{HNO}_3 \) and \(\text{SO}_4^{2-} \)), and the products \(\text{HSO}_4^{-} \) and \(\text{NO}_3^{-}\)).
08

- Identify the Acid and Base (Reaction c)

Determine which species donates a proton (\( \text{H}^+ \)). \(\text{HNO}_3 \) donates a proton to \(\text{SO}_4^{2-} \) forming \(\text{HSO}_4^{-} \), making \(\text{HNO}_3 \) the acid and \(\text{SO}_4^{2-} \) the base.
09

- Identify the Conjugate Pairs (Reaction c)

Identify the conjugate acid-base pairs: \(\text{HNO}_3 \) (acid) and \(\text{NO}_3^{-} \) (conjugate base), and \(\text{SO}_4^{2-} \) (base) and \(\text{HSO}_4^{-} \) (conjugate acid).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Proton Donor
In acid-base chemistry, a proton donor is considered the acid. An acid donates a proton \(( \text{H}^+ \)) to another species. For example, in the reaction of acetic acid ( \(\text{CH}_3\text{COOH} \)) with water ( \(\text{H}_2\text{O} \)), \(\text{CH}_3\text{COOH} \) is the proton donor as it gives up an \(\text{H}^+ \) ion to \(\text{H}_2\text{O} \), forming hydronium ( \(\text{H}_3\text{O}^+ \)) and acetate ( \(\text{CH}_3\text{COO}^- \)). Similarly, bicarbonate ( \(\text{HCO}_3^- \)) donates a proton to water forming carbonic acid ( \(\text{H}_2\text{CO}_3 \)) in another reaction. In the case of nitric acid reacting with sulfate, \(\text{HNO}_3 \) donates a proton to \(\text{SO}_4^{2-} \) to produce \(\text{HSO}_4^- \) and \(\text{NO}_3^- \).
Proton Acceptor
A proton acceptor is also known as a base in acid-base reactions. A base accepts a proton \(( \text{H}^+ \)) from an acid. For instance, in the reaction where water acts as a proton acceptor from acetic acid, water \(( \text{H}_2\text{O} \)) accepts an \(\text{H}^+ \) ion from \(\text{CH}_3\text{COOH} \), resulting in the formation of hydronium ion \(( \text{H}_3\text{O}^+ \)). Likewise, in a bicarbonate-water reaction, water acts as the proton acceptor forming hydroxide ion \(( \text{OH}^- \)). In the nitric acid and sulfate reaction, \(\text{SO}_4^{2-} \) accepts a proton to form \(\text{HSO}_4^- \).
Conjugate Acid-Base Pair
In acid-base reactions, every acid has a conjugate base, and every base has a conjugate acid. The conjugate base is what remains after the acid donates a proton, while the conjugate acid is what forms when the base accepts a proton. For example, when \(\text{CH}_3\text{COOH} \) (acetic acid) donates a proton, it becomes \(\text{CH}_3\text{COO}^- \) (acetate), its conjugate base. When water \(( \text{H}_2\text{O} \)) accepts a proton, it becomes \(\text{H}_3\text{O}^+ \) (hydronium), its conjugate acid. Similarly, \(\text{HCO}_3^- \) (bicarbonate) turns into \(\text{CO}_3^{2-} \) after donating a proton, and water turns into \(\text{OH}^- \) after accepting a proton. In the reaction involving \(\text{HNO}_3 \) (nitric acid), its conjugate base is \(\text{NO}_3^- \), while \(\text{HSO}_4^- \) is the conjugate acid of \(\text{SO}_4^{2-} \).
Acetic Acid
Acetic acid ( \(\text{CH}_3\text{COOH} \)) is a common weak acid found in vinegar. When acetic acid reacts with water, it donates a proton forming its conjugate base, acetate \(\text{CH}_3\text{COO}^- \). In this reaction, the water molecule acts as the base, accepting the proton and forming hydronium ion \(\text{H}_3\text{O}^+ \). Acetic acid's role in many biochemical processes and its presence in daily life makes it an important substance to understand. Its chemical structure allows it to donate a proton, typical of weak acids, which only partially ionize in solution.
Bicarbonate
Bicarbonate ion \(\text{HCO}_3^- \) plays a key role in maintaining the pH balance in blood and other bodily fluids. In water, bicarbonate can react as an acid by donating a proton, forming carbonic acid \(\text{H}_2\text{CO}_3 \), or as a base by accepting a proton, resulting in carbonate \(\text{CO}_3^{2-} \). This dual capability makes bicarbonate a crucial buffer in physiological systems. For example, in the given reaction, \(\text{HCO}_3^- \) donates a proton to \(\text{H}_2\text{O} \), forming carbonic acid and \(\text{OH}^- \). This reversible reaction helps regulate pH by neutralizing acids and bases.
Nitric Acid
Nitric acid ( \(\text{HNO}_3 \)) is a strong acid commonly used in laboratory and industrial applications. It readily donates a proton to bases. When nitric acid reacts with \(\text{SO}_4^{2-} \) (sulfate ion), it donates a proton to form \(\text{HSO}_4^- \) (bisulfate) and \(\text{NO}_3^- \) (nitrate ion). Since nitric acid is a strong acid, it completely ionizes in solution, meaning it fully dissociates to release its \(\text{H}^+ \) ions. This characteristic is important in reactions that require a strong protic environment and explains its prominence in various chemical processes.

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Most popular questions from this chapter

Compare the general properties of acids with the general properties of bases.

A seashell that is composed largely of calcium carbonate reacts with a solution of HCl. As a result, 1500 \(\mathrm{mL}\) of dry \(\mathrm{CO}_{2}\) gas at STP is produced. The other products are CaCl, and \(\mathrm{H}_{2} \mathrm{O}\) . a. How many grams of \(\mathrm{CaCO}_{3}\) are consumed in the reaction? b. What volume of 2.00 \(\mathrm{M}\) HCl solution is used in this reaction?

a. What determines the strength of an Arrhenius base? b. Give one example each of an aqueous solution of a strong base and an aqueous solution of a weak base.

a. Distinguish between binary acids and oxyacids in terms of their component elements and the systems used in naming them. b. Give three examples of each type of acid.

Acid precipitation is the term generally used to describe rain or snow that is more acidic than it normally is. One cause of acid precipitation is the formation of sulfuric and nitric acids from various sulfur and nitrogen oxides produced in volcanic eruptions, forest fires, and thunderstorms. In a typical volcanic eruption, for example, \(3.50 \times 10^{8} \mathrm{kg} \mathrm{SO}_{2}\) may be produced. If this amount of \(\mathrm{SO}_{2}\) were converted to \(\mathrm{H}_{2} \mathrm{SO}_{4}\) according to the two-step process given below, how many kilograms of \(\mathrm{H}_{2} \mathrm{SO}_{4}\) would be produced from such an eruption? $$ \begin{array}{c}{\mathrm{SO}_{2}+\frac{1}{2} \mathrm{O}_{2} \longrightarrow \mathrm{SO}_{3}} \\ {\mathrm{SO}_{3}+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{H}_{2} \mathrm{SO}_{4}}\end{array} $$

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