Chapter 5: Problem 29
What are standard temperature and pressure (STP)? What is the significance of STP in relation to the volume of 1 mole of an ideal gas?
Chapter 5: Problem 29
What are standard temperature and pressure (STP)? What is the significance of STP in relation to the volume of 1 mole of an ideal gas?
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Get started for freeThe volume of a gas is \(5.80 \mathrm{~L}\), measured at 1.00 atm. What is the pressure of the gas in \(\mathrm{mmHg}\) if the volume is changed to \(9.65 \mathrm{~L} ?\) (The temperature remains constant.)
Convert \(562 \mathrm{mmHg}\) to atm.
At \(27^{\circ} \mathrm{C}, 10.0\) moles of a gas in a \(1.50-\mathrm{L}\) container exert a pressure of 130 atm. Is this an ideal gas?
Estimate the distance (in nanometers) between molecules of water vapor at \(100^{\circ} \mathrm{C}\) and \(1.0 \mathrm{~atm}\). Assume ideal behavior. Repeat the calculation for liquid water at \(100^{\circ} \mathrm{C}\), given that the density of water is \(0.96 \mathrm{~g} / \mathrm{cm}^{3}\) at that temperature. Comment on your results. (Assume water molecule to be a sphere with a diameter of \(0.3 \mathrm{nm} .\) )
The apparatus shown in the diagram can be used to measure atomic and molecular speed. Suppose that a beam of metal atoms is directed at a rotating cylinder in a vacuum. A small opening in the cylinder allows the atoms to strike a target area. Because the cylinder is rotating, atoms traveling at different speeds will strike the target at different positions. In time, a layer of the metal will deposit on the target area, and the variation in its thickness is found to correspond to Maxwell's speed distribution. In one experiment it is found that at \(850^{\circ} \mathrm{C}\) some bismuth (Bi) atoms struck the target at a point \(2.80 \mathrm{~cm}\) from the spot directly opposite the slit. The diameter of the cylinder is \(15.0 \mathrm{~cm}\) and it is rotating at 130 revolutions per second. (a) Calculate the speed \((\mathrm{m} / \mathrm{s})\) at which the target is moving. (Hint: The circumference of a circle is given by \(2 \pi r\), in which \(r\) is the radius.) (b) Calculate the time (in seconds) it takes for the target to travel \(2.80 \mathrm{~cm} .\) (c) Determine the speed of the Bi atoms. Compare your result in (c) with the \(u_{\mathrm{rms}}\) of Bi at \(850^{\circ} \mathrm{C}\). Comment on the difference.
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