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Describe how to prepare \(1.00 \mathrm{~L}\) of \(0.646 \mathrm{M} \mathrm{HCl}\) solution, starting with a \(2.00 \mathrm{M} \mathrm{HCl}\) solution.

Short Answer

Expert verified
To prepare a \(1.00 \mathrm{~L}\) of \(0.646 \mathrm{M} \mathrm{HCl}\) solution, one would need to take \(0.323 \mathrm{L}\) (or \(323 \mathrm{mL}\)) of the \(2.00 \mathrm{M} \mathrm{HCl}\) solution and then dilute it with water until the total volume of the solution becomes \(1.00 \mathrm{L}\).

Step by step solution

01

Identify the known values

In this case, we know the initial molarity \(M1 = 2.00 \mathrm{M}\), final molarity \(M2 = 0.646 \mathrm{M}\) and final volume \(V2 = 1.00 \mathrm{L}\). The initial volume \(V1\) for the more concentrated solution is what we need to find.
02

Apply the dilution formula

Apply the formula \(M1V1 = M2V2\) by substituting the known values into it. This would look like \(2.00 \mathrm{M} * V1 = 0.646 \mathrm{M} * 1.00 \mathrm{L}\)
03

Solve for \(V1\)

To get the volume \(V1\), you would then divide both sides of the equation by \(2.00 \mathrm{M}\). This yields: \(V1 = (0.646 \mathrm{M} * 1.00 \mathrm{L}) / 2.00 \mathrm{M}\)
04

Calculate the Volume

After performing the division, the resulting volume \(V1\) is therefore the amount of the \(2.00 \mathrm{M} \mathrm{HCl}\) solution required to make \(1.00 \mathrm{L}\) of a \(0.646 \mathrm{M} \mathrm{HCl}\) solution.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Solution Preparation
Preparing a solution involves taking a concentrated solution and diluting it to achieve a desired concentration. This process often requires precise measurements to ensure accuracy. It is essential to have a clear understanding of the concentration before starting.
One begins this process by determining the initial and final concentrations and volumes. In the given example, you start with a concentrated hydrochloric acid ( HCl ) solution with a molarity of 2.00 M, and the goal is to prepare 1.00 L of a less concentrated solution with a molarity of 0.646 M.
Accurate measurements of volume are crucial during this process. It is common practice to use a pipette to measure liquid volumes precisely. Once the correct amount of concentrated solution has been measured, it is then diluted with a solvent, usually water, to reach the desired concentration. Proper safety measures, including the use of gloves and goggles, should be taken when handling chemicals.
Concentration
Concentration describes the amount of solute present in a given volume of solution. It is crucial for determining the properties and behavior of the solution. In chemistry, concentration can be expressed in various ways, but molarity is one of the most commonly used.
Molarity (M) is defined as the number of moles of solute per liter of solution. When preparing solutions, adjusting concentration involves adding or removing solvent to change this ratio.
  • If you increase the amount of solvent, the concentration decreases, which is called dilution.
  • Conversely, reducing the volume of solvent increases the concentration, known as concentration.
Understanding concentration allows chemists to predict how substances will interact in reactions, making it a critical concept in solution chemistry.
Molarity Formula
The molarity formula is essential for calculating how to dilute a solution correctly. It provides a relationship between the volume and concentration of two solutions.
The formula is expressed as: \(M1 \times V1 = M2 \times V2\)
In this equation:
  • \(M1\) is the molarity of the concentrated solution.
  • \(V1\) is the volume of the concentrated solution needed.
  • \(M2\) is the molarity of the diluted solution.
  • \(V2\) is the final volume of the diluted solution.
By rearranging this equation, one can solve for any of the unknown variables. This formula helps ensure precise solution preparation, providing accurate results crucial for experimentation and analysis. For example, when given all variables except \(V1\), one can rearrange to solve for \(V1\) and find the amount of the concentrated solution to use.
Chemical Solutions
Chemical solutions are homogeneous mixtures of two or more substances. They involve a solute, often a solid or gas, dissolved in a solvent, usually a liquid.
For example, in an HCl solution, HCl gas is the solute, and water is the solvent.
Properties of chemical solutions, such as conductivity, reactivity, and boiling or freezing points, depend heavily on their concentration. Precise control over these properties is vital in fields ranging from industrial processes to medical applications.
  • In medical settings, precise concentrations of solutions are crucial for effective treatment.
  • In labs, consistency and reliability of chemical reactions often rely on exact solution concentrations.
Understanding how to calculate and manipulate these properties is key for success in chemistry and many fields that rely on chemical solutions.

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Most popular questions from this chapter

A \(60.0-\mathrm{mL} 0.513 \mathrm{M}\) glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)\) solution is mixed with \(120.0 \mathrm{~mL}\) of \(2.33 \mathrm{M}\) glucose solution. What is the concentration of the final solution? Assume the volumes are additive.

A \(1.00-\mathrm{g}\) sample of a metal \(\mathrm{X}\) (that is known to form \(\mathrm{X}^{2+}\) ions) was added to a \(0.100 \mathrm{~L}\) of \(0.500 \mathrm{M}\) \(\mathrm{H}_{2} \mathrm{SO}_{4}\). After all the metal had reacted, the remaining acid required \(0.0334 \mathrm{~L}\) of \(0.500 \mathrm{M} \mathrm{NaOH}\) solution for neutralization. Calculate the molar mass of the metal and identify the element.

Magnesium is a valuable, lightweight metal. It is used as a structural metal and in alloys, in batteries, and in chemical synthesis. Although magnesium is plentiful in Earth's crust, it is cheaper to "mine" the metal from seawater. Magnesium forms the second most abundant cation in the sea (after sodium); there are about \(1.3 \mathrm{~g}\) of magnesium in \(1 \mathrm{~kg}\) of seawater. The method of obtaining magnesium from seawater employs all three types of reactions discussed in this chapter: precipitation, acid-base, and redox reactions. In the first stage in the recovery of magnesium, limestone \(\left(\mathrm{CaCO}_{3}\right)\) is heated at high temperatures to produce quicklime, or calcium oxide \((\mathrm{CaO})\) : $$ \mathrm{CaCO}_{3}(s) \longrightarrow \mathrm{CaO}(s)+\mathrm{CO}_{2}(g) $$ When calcium oxide is treated with seawater, it forms calcium hydroxide \(\left[\mathrm{Ca}(\mathrm{OH})_{2}\right]\), which is slightly soluble and ionizes to give \(\mathrm{Ca}^{2+}\) and \(\mathrm{OH}^{-}\) ions: $$ \mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}^{2+}(a q)+2 \mathrm{OH}^{-}(a q) $$ The surplus hydroxide ions cause the much less soluble magnesium hydroxide to precipitate: $$ \mathrm{Mg}^{2+}(a q)+2 \mathrm{OH}^{-}(a q) \longrightarrow \mathrm{Mg}(\mathrm{OH})_{2}(s) $$ The solid magnesium hydroxide is filtered and reacted with hydrochloric acid to form magnesium chloride \(\left(\mathrm{MgCl}_{2}\right)\) \(\mathrm{Mg}(\mathrm{OH})_{2}(s)+2 \mathrm{HCl}(a q) \longrightarrow\) $$ \mathrm{MgCl}_{2}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ After the water is evaporated, the solid magnesium chloride is melted in a steel cell. The molten magnesium chloride contains both \(\mathrm{Mg}^{2+}\) and \(\mathrm{Cl}^{-}\) ions. In a process called electrolysis, an electric current is passed through the cell to reduce the \(\mathrm{Mg}^{2+}\) ions and oxidize the \(\mathrm{Cl}^{-}\) ions. The halfreactions are $$ \begin{aligned} \mathrm{Mg}^{2+}+2 e^{-} \longrightarrow \mathrm{Mg} \\ 2 \mathrm{Cl}^{-} \longrightarrow \mathrm{Cl}_{2}+2 e^{-} \end{aligned} $$ The overall reaction is $$ \mathrm{MgCl}_{2}(l) \longrightarrow \mathrm{Mg}(s)+\mathrm{Cl}_{2}(g) $$ This is how magnesium metal is produced. The chlorine gas generated can be converted to hydrochloric acid and recycled through the process. (a) Identify the precipitation, acid-base, and redox processes. (b) Instead of calcium oxide, why don't we simply add sodium hydroxide to precipitate magnesium hydroxide? (c) Sometimes a mineral called dolomite (a combination of \(\mathrm{CaCO}_{3}\) and \(\mathrm{MgCO}_{3}\) ) is substituted for limestone \(\left(\mathrm{CaCO}_{3}\right)\) to bring about the precipitation of magnesium hydroxide. What is the advantage of using dolomite? (d) What are the advantages of mining magnesium from the ocean rather than from Earth's crust?

Hydrogen halides (HF, HCl, HBr, HI) are highly reactive compounds that have many industrial and laboratory uses. (a) In the laboratory, HF and HCl can be generated by reacting \(\mathrm{CaF}_{2}\) and \(\mathrm{NaCl}\) with concentrated sulfuric acid. Write appropriate equations for the reactions. (Hint: These are not redox reactions.) (b) Why is it that HBr and HI cannot be prepared similarly, that is, by reacting \(\mathrm{NaBr}\) and \(\mathrm{NaI}\) with concentrated sulfuric acid? (Hint: \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is a stronger oxidizing agent than both \(\mathrm{Br}_{2}\) and \(\mathrm{I}_{2} .\) ) (c) \(\mathrm{HBr}\) can be prepared by reacting phosphorus tribromide \(\left(\mathrm{PBr}_{3}\right)\) with water. Write an equation for this reaction.

If \(30.0 \mathrm{~mL}\) of \(0.150 \mathrm{M} \mathrm{CaCl}_{2}\) is added to \(15.0 \mathrm{~mL}\) of \(0.100 \mathrm{MAgNO}_{3}\), what is the mass in grams of \(\mathrm{AgCl}\) precipitate?

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